A promising sol-gel route to suppress pyrochlore phase during the synthesis of multiferroic Pb(Fe2/3W1/3)O-3 using inorganic salts
文献类型:期刊论文
作者 | Yao, C. F.1; Liu, Z. Q.1; Shang, J. K.1,2 |
刊名 | JOURNAL OF ALLOYS AND COMPOUNDS
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出版日期 | 2010-07-23 |
卷号 | 502期号:2页码:429-433 |
关键词 | Sol-gel Perovskite Pb(Fe2/3W1/3)O-3 Pyrochlore Morphology |
ISSN号 | 0925-8388 |
DOI | 10.1016/j.jallcom.2010.04.190 |
通讯作者 | Liu, Z. Q.(zqliu@imr.ac.cn) |
英文摘要 | This paper reports a promising route to synthesize multiferroic Pb(Fe2/3W1/3)O-3 by sol-gel method with inorganic salts of (CH3COO)(2)Pb center dot H2O, Fe(NO3)(3)center dot 9H(2)O, and (NH4)5H(5)[H-2(WO4)(6)]center dot H2O.The pyrochlore phase was largely suppressed by increasing the calcination temperature, and high purity of perovskite phase was obtained at 725 degrees C which is much lower than the temperature used in other synthesizing processes. Microstructural investigations revealed that the synthesized Pb(Fe2/3W1/3)O-3 particles have cubic morphology and superlattice crystal structure. The formation of Pb(Fe2/3W1/3)O-3 was not sensitive to the pH value of the solution, which is another advantage of this sol-gel method. (C) 2010 Elsevier B.V. All rights reserved. |
资助项目 | National Basic Research Program of China[2010CB631006] ; Chinese Academy of Sciences |
WOS研究方向 | Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering |
语种 | 英语 |
WOS记录号 | WOS:000280471100035 |
出版者 | ELSEVIER SCIENCE SA |
资助机构 | National Basic Research Program of China ; Chinese Academy of Sciences |
源URL | [http://ir.imr.ac.cn/handle/321006/100431] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
通讯作者 | Liu, Z. Q. |
作者单位 | 1.Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang 110016, Peoples R China 2.Univ Illinois, Dept Mat Sci & Engn, Urbana, IL 61801 USA |
推荐引用方式 GB/T 7714 | Yao, C. F.,Liu, Z. Q.,Shang, J. K.. A promising sol-gel route to suppress pyrochlore phase during the synthesis of multiferroic Pb(Fe2/3W1/3)O-3 using inorganic salts[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2010,502(2):429-433. |
APA | Yao, C. F.,Liu, Z. Q.,&Shang, J. K..(2010).A promising sol-gel route to suppress pyrochlore phase during the synthesis of multiferroic Pb(Fe2/3W1/3)O-3 using inorganic salts.JOURNAL OF ALLOYS AND COMPOUNDS,502(2),429-433. |
MLA | Yao, C. F.,et al."A promising sol-gel route to suppress pyrochlore phase during the synthesis of multiferroic Pb(Fe2/3W1/3)O-3 using inorganic salts".JOURNAL OF ALLOYS AND COMPOUNDS 502.2(2010):429-433. |
入库方式: OAI收割
来源:金属研究所
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