Studies of the Local Structure and the g Factors of the Cu2+ Site in Y2BaCuO5
文献类型:期刊论文
作者 | Zhang, H. M.1; Wu, S. Y.1,2; Hu, Y. X.1; Wang, X. F.1 |
刊名 | JOURNAL OF SUPERCONDUCTIVITY AND NOVEL MAGNETISM
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出版日期 | 2010-07-01 |
卷号 | 23期号:5页码:833-835 |
关键词 | Crystal fields and spin Hamiltonians Electron paramagnetic resonance Cu2+ Y2BaCuO5 |
ISSN号 | 1557-1939 |
DOI | 10.1007/s10948-009-0614-7 |
通讯作者 | Zhang, H. M.(huamingzhang66@gmail.com) |
英文摘要 | The local structure and the g factors (g(x), g(y), and g(z)) of the Cu2+ site in Y2BaCuO5 are theoretically studied using the perturbation formulas of the g factors for a 3d(9) ion in orthorhombically elongated octahedra. The orthorhombic field parameters in these formulas are determined from the superposition model and the local geometry of the system. From the calculations, the oxygen octahedron is found to undergo the local elongation Delta Z (approximate to 0.05 angstrom) along c-axis and the relative bond length variation Delta X (approximate to 0.1 angstrom) along a- and b-axes, respectively. The calculated g factors based on the above local structure are in good agreement with the experimental data. The relationships between the anisotropies of the g factors and the low symmetrical (orthorhombic) distortions of the Cu2+ site in Y2BaCuO5 are discussed. |
WOS研究方向 | Physics |
语种 | 英语 |
WOS记录号 | WOS:000278546800055 |
出版者 | SPRINGER |
源URL | [http://ir.imr.ac.cn/handle/321006/100697] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
通讯作者 | Zhang, H. M. |
作者单位 | 1.Univ Elect Sci & Technol China, Dept Appl Phys, Chengdu 610054, Peoples R China 2.Chinese Acad Sci, Int Ctr Mat Phys, Shenyang 110016, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, H. M.,Wu, S. Y.,Hu, Y. X.,et al. Studies of the Local Structure and the g Factors of the Cu2+ Site in Y2BaCuO5[J]. JOURNAL OF SUPERCONDUCTIVITY AND NOVEL MAGNETISM,2010,23(5):833-835. |
APA | Zhang, H. M.,Wu, S. Y.,Hu, Y. X.,&Wang, X. F..(2010).Studies of the Local Structure and the g Factors of the Cu2+ Site in Y2BaCuO5.JOURNAL OF SUPERCONDUCTIVITY AND NOVEL MAGNETISM,23(5),833-835. |
MLA | Zhang, H. M.,et al."Studies of the Local Structure and the g Factors of the Cu2+ Site in Y2BaCuO5".JOURNAL OF SUPERCONDUCTIVITY AND NOVEL MAGNETISM 23.5(2010):833-835. |
入库方式: OAI收割
来源:金属研究所
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