A theoretical study of EPR g factors for the rhombic CuCl64- clusters in (3-chloroanilinium)(8)[CdCl6]Cl-4:Cu2+ crystal
文献类型：期刊论文
| 作者 | Zhang Dong-Ting1; He Lv2; Yang Wei-Qing1,3; Zheng Wen-Chen1,4 |
| 刊名 | PHYSICA B-CONDENSED MATTER
 |
| 出版日期 | 2010-09-01 |
| 卷号 | 405期号:17页码:3642-3644 |
| 关键词 | Electron paramagnetic resonance Crystal and ligand field theory Optical spectrum (3-chloroanilinium)(8)[CdCl6]Cl-4:Cu2+ |
| ISSN号 | 0921-4526 |
| DOI | 10.1016/j.physb.2010.05.057 |
| 通讯作者 | Zheng Wen-Chen(zhengwc1@163.com) |
| 英文摘要 | In this paper, the third-order perturbation formulas of EPR g factors g(i) (i=x, y, z) for d(9) ions in rhombic symmetry where the ground state being an vertical bar d(x2-y2)> admixture of and vertical bar d(z2)> states are derived. These formulas are based on a two-spin-orbit-parameter model in which the contributions to g factors due to both the spin-orbit parameter of the central 3d(n) ion and that of ligand ion are included. From these formulas, the g factors g(i) for the rhombic CuCl64- clusters in (3-chloroanilinium)(8)[CdCl6]CL4:Cu2+ crystal are calculated. The calculated values are in good agreement with those obtained by the complete diagonalization (of energy matrix) method and experimental values. Results are discussed. (C) 2010 Elsevier B.V. All rights reserved. |
| WOS研究方向 | Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000280897500026 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.imr.ac.cn/handle/321006/102797]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Zheng Wen-Chen |
| 作者单位 | 1.Sichuan Univ, Dept Mat Sci, Chengdu 610064, Peoples R China 2.Zhejiang Normal Univ, Dept Phys, Jinhua 321004, Peoples R China 3.Chengdu Univ Informat Technol, Dept Opt & Elect, Chengdu 610225, Peoples R China 4.Chinese Acad Sci, Int Ctr Mat Phys, Shenyang 110016, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang Dong-Ting,He Lv,Yang Wei-Qing,et al. A theoretical study of EPR g factors for the rhombic CuCl64- clusters in (3-chloroanilinium)(8)[CdCl6]Cl-4:Cu2+ crystal[J]. PHYSICA B-CONDENSED MATTER,2010,405(17):3642-3644. |
| APA | Zhang Dong-Ting,He Lv,Yang Wei-Qing,&Zheng Wen-Chen.(2010).A theoretical study of EPR g factors for the rhombic CuCl64- clusters in (3-chloroanilinium)(8)[CdCl6]Cl-4:Cu2+ crystal.PHYSICA B-CONDENSED MATTER,405(17),3642-3644. |
| MLA | Zhang Dong-Ting,et al."A theoretical study of EPR g factors for the rhombic CuCl64- clusters in (3-chloroanilinium)(8)[CdCl6]Cl-4:Cu2+ crystal".PHYSICA B-CONDENSED MATTER 405.17(2010):3642-3644. |
入库方式： OAI收割
来源：金属研究所
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