Theoretical investigation for the EPR g-factors of the mixed ground state in NaCl: Ag2+ crystals
文献类型：期刊论文
| 作者 | Li, W. L.1; Li, X. M.1,2; Feng, W. L.1,3,4; Yang, W. J.2; Tao, C. Y.1 |
| 刊名 | SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
 |
| 出版日期 | 2011-09-01 |
| 卷号 | 79期号:5页码:1308-1310 |
| 关键词 | Electron paramagnetic resonance Double spin-orbit coupling model NaCl Ag2+ |
| ISSN号 | 1386-1425 |
| DOI | 10.1016/j.saa.2011.04.060 |
| 通讯作者 | Li, X. M.(xuemingli@cqu.edu.cn) |
| 英文摘要 | In this paper, it is considered that the local structure of the (AgCl6)(4-) cluster for the NaCI: Ag2+ crystal is of the axially elongational D-4h symmetry which possesses the weaker rhombic distortion at < 001 > lattice site. The mechanism for an admixture of the (2)A(1g) into the ground state B-2(1g) is taken into account. The electron paramagnetic resonance (EPR)g factors of NaCl: Ag2+ are studied by using the double spin-orbit coupling model and an approximation of a semiempirical molecular orbit. The EPR g factors for the NaCl: Ag2+ crystals are reasonably explained as well as the good agreement between the calculated values and the experimental data is obtained. (C) 2011 Elsevier B.V. All rights reserved. |
| 资助项目 | National Science Foundation for Postdoctoral Scientists of China[20100470811] ; Natural Science Foundation, Education Commission of Chongqing, China[KJ090608] ; Fundamental Research Funds for the Central Universities[CDJXS10122217] |
| WOS研究方向 | Spectroscopy |
| 语种 | 英语 |
| WOS记录号 | WOS:000293363000068 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 资助机构 | National Science Foundation for Postdoctoral Scientists of China ; Natural Science Foundation, Education Commission of Chongqing, China ; Fundamental Research Funds for the Central Universities |
| 源URL | [http://ir.imr.ac.cn/handle/321006/104462]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Li, X. M. |
| 作者单位 | 1.Chongqing Univ, Coll Optoelect Engn, Minist Educ, Key Lab Optoelect Technol & Syst, Chongqing 400044, Peoples R China 2.Chongqing Univ, Coll Chem & Chem Engn, Chongqing 400044, Peoples R China 3.Chongqing Univ Technol, Dept Appl Phys, Chongqing 400054, Peoples R China 4.Chinese Acad Sci, Int Ctr Mat Phys, Shenyang 110016, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, W. L.,Li, X. M.,Feng, W. L.,et al. Theoretical investigation for the EPR g-factors of the mixed ground state in NaCl: Ag2+ crystals[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,2011,79(5):1308-1310. |
| APA | Li, W. L.,Li, X. M.,Feng, W. L.,Yang, W. J.,&Tao, C. Y..(2011).Theoretical investigation for the EPR g-factors of the mixed ground state in NaCl: Ag2+ crystals.SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,79(5),1308-1310. |
| MLA | Li, W. L.,et al."Theoretical investigation for the EPR g-factors of the mixed ground state in NaCl: Ag2+ crystals".SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 79.5(2011):1308-1310. |
入库方式： OAI收割
来源：金属研究所
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