Microstructure, electrochemical performance and gas-phase hydrogen storage property of Zr0.9Ti0.1[(Ni,V,Mn)(0.95)Co-0.05](alpha) laves phase alloys
文献类型:期刊论文
作者 | Yang, K; Chen, DM; Chen, L; Guo, ZX |
刊名 | JOURNAL OF ALLOYS AND COMPOUNDS
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出版日期 | 2002-02-14 |
卷号 | 333期号:1-2页码:184-189 |
关键词 | transition metal compounds electrode materials energy storage materials gas-solid reactions electrochemical reactions |
ISSN号 | 0925-8388 |
通讯作者 | Guo, ZX() |
英文摘要 | A series of Zr0.9Ti0.1 [(NiVMn)(0.95)Co-0.05](alpha) alloys were prepared by vacuum induction melting to investigate the relationship between the composition and the electrochemical performance of AB, alloys. It was shown that the electrochemical capacity is improved, but the cycle life is reduced, when increasing the content of Mn and decreasing that of Ni in the alloys, keeping the contents of the other elements constant. The electrochemical capacity is increased, but the high-rate capability deteriorated with the increasing level of the V and the decrease of Ni in the alloys. The effects are attributed to the electro-catalyzing effect of Ni, the dissolution of Mn into the alkaline solution and the change of hydrogen affinity resulting from the substitution of V for Ni. (C) 2002 Elsevier Science B.V. All rights reserved. |
WOS研究方向 | Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering |
语种 | 英语 |
WOS记录号 | WOS:000173481300032 |
出版者 | ELSEVIER SCIENCE SA |
源URL | [http://ir.imr.ac.cn/handle/321006/114128] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
通讯作者 | Guo, ZX |
作者单位 | 1.Chinese Acad Sci, Inst Met Res, Shenyang 110015, Peoples R China 2.Univ London, Dept Mat, London E1 4NS, England |
推荐引用方式 GB/T 7714 | Yang, K,Chen, DM,Chen, L,et al. Microstructure, electrochemical performance and gas-phase hydrogen storage property of Zr0.9Ti0.1[(Ni,V,Mn)(0.95)Co-0.05](alpha) laves phase alloys[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2002,333(1-2):184-189. |
APA | Yang, K,Chen, DM,Chen, L,&Guo, ZX.(2002).Microstructure, electrochemical performance and gas-phase hydrogen storage property of Zr0.9Ti0.1[(Ni,V,Mn)(0.95)Co-0.05](alpha) laves phase alloys.JOURNAL OF ALLOYS AND COMPOUNDS,333(1-2),184-189. |
MLA | Yang, K,et al."Microstructure, electrochemical performance and gas-phase hydrogen storage property of Zr0.9Ti0.1[(Ni,V,Mn)(0.95)Co-0.05](alpha) laves phase alloys".JOURNAL OF ALLOYS AND COMPOUNDS 333.1-2(2002):184-189. |
入库方式: OAI收割
来源:金属研究所
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