Crystal structure and magnetic properties Nd4Ga2O9 and Sm4Ga2O9
文献类型:期刊论文
作者 | Liu, FS; Liu, QL; Liang, JK; Song, GB; Luo, J; Yang, LT; Zhang, Y; Rao, GH |
刊名 | JOURNAL OF ALLOYS AND COMPOUNDS
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出版日期 | 2004-11-03 |
卷号 | 381期号:1-2页码:26-31 |
关键词 | Nd4Ga2O9 Sm4Ga2O9 crystal structure Rietveld refinement x-ray diffraction |
ISSN号 | 0925-8388 |
DOI | 10.1016/j.jallcom.2004.04.072 |
通讯作者 | Liu, FS(fsliu@aphy.iphy.ac.cn) |
英文摘要 | The crystal structures of Nd4Ga2O9 and Sm4Ga2O9 compounds synthesized by solid-state reaction at 1400degreesC are investigated. X-ray diffraction shows that Nd4Ga2O9 and Sm4Ga2O9 are monoclinic system with the space group P2(1)/c, and lattice parameters a = 7.7656(1) Angstrom, b = 10.9689(1) Angstrom, c = 11.4727(1) Angstrom, beta = 109.06(1)degrees for Nd4Ga2O9, and a = 7.6613(1) Angstrom, b = 10.8546(1) Angstrom, c = 11.4080(1) Angstrom, beta = 108.80(1)degrees for Sm4Ga2O9. The gallium atoms are in the center of distorted oxygen tetrahedra with an average Ga-O bond distance between 1.82 and 1.85 Angstrom. The rare earth atoms are sixfold or sevenfold coordinated by oxygen. The oxygen atoms are threefold and fourfold coordinated. The magnetization for these compounds clearly reflects paramagnetism. The magnetic susceptibility chi changes with temperature in a Curie-type manner. (C) 2004 Elsevier B.V All rights reserved. |
WOS研究方向 | Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering |
语种 | 英语 |
WOS记录号 | WOS:000224762300006 |
出版者 | ELSEVIER SCIENCE SA |
源URL | [http://ir.imr.ac.cn/handle/321006/119389] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
通讯作者 | Liu, FS |
作者单位 | 1.Acad Sinica, Int Ctr Mat Phys, Shenyang 110016, Peoples R China 2.SW Univ Sci & Technol, Coll Mat Sci & Engn, Mianyang 621002, Peoples R China 3.Chinese Acad Sci, Inst Phys, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, FS,Liu, QL,Liang, JK,et al. Crystal structure and magnetic properties Nd4Ga2O9 and Sm4Ga2O9[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2004,381(1-2):26-31. |
APA | Liu, FS.,Liu, QL.,Liang, JK.,Song, GB.,Luo, J.,...&Rao, GH.(2004).Crystal structure and magnetic properties Nd4Ga2O9 and Sm4Ga2O9.JOURNAL OF ALLOYS AND COMPOUNDS,381(1-2),26-31. |
MLA | Liu, FS,et al."Crystal structure and magnetic properties Nd4Ga2O9 and Sm4Ga2O9".JOURNAL OF ALLOYS AND COMPOUNDS 381.1-2(2004):26-31. |
入库方式: OAI收割
来源:金属研究所
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