中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Crystal structure and magnetic properties Nd4Ga2O9 and Sm4Ga2O9

文献类型:期刊论文

作者Liu, FS; Liu, QL; Liang, JK; Song, GB; Luo, J; Yang, LT; Zhang, Y; Rao, GH
刊名JOURNAL OF ALLOYS AND COMPOUNDS
出版日期2004-11-03
卷号381期号:1-2页码:26-31
关键词Nd4Ga2O9 Sm4Ga2O9 crystal structure Rietveld refinement x-ray diffraction
ISSN号0925-8388
DOI10.1016/j.jallcom.2004.04.072
通讯作者Liu, FS(fsliu@aphy.iphy.ac.cn)
英文摘要The crystal structures of Nd4Ga2O9 and Sm4Ga2O9 compounds synthesized by solid-state reaction at 1400degreesC are investigated. X-ray diffraction shows that Nd4Ga2O9 and Sm4Ga2O9 are monoclinic system with the space group P2(1)/c, and lattice parameters a = 7.7656(1) Angstrom, b = 10.9689(1) Angstrom, c = 11.4727(1) Angstrom, beta = 109.06(1)degrees for Nd4Ga2O9, and a = 7.6613(1) Angstrom, b = 10.8546(1) Angstrom, c = 11.4080(1) Angstrom, beta = 108.80(1)degrees for Sm4Ga2O9. The gallium atoms are in the center of distorted oxygen tetrahedra with an average Ga-O bond distance between 1.82 and 1.85 Angstrom. The rare earth atoms are sixfold or sevenfold coordinated by oxygen. The oxygen atoms are threefold and fourfold coordinated. The magnetization for these compounds clearly reflects paramagnetism. The magnetic susceptibility chi changes with temperature in a Curie-type manner. (C) 2004 Elsevier B.V All rights reserved.
WOS研究方向Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering
语种英语
WOS记录号WOS:000224762300006
出版者ELSEVIER SCIENCE SA
源URL[http://ir.imr.ac.cn/handle/321006/119389]  
专题金属研究所_中国科学院金属研究所
通讯作者Liu, FS
作者单位1.Acad Sinica, Int Ctr Mat Phys, Shenyang 110016, Peoples R China
2.SW Univ Sci & Technol, Coll Mat Sci & Engn, Mianyang 621002, Peoples R China
3.Chinese Acad Sci, Inst Phys, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Liu, FS,Liu, QL,Liang, JK,et al. Crystal structure and magnetic properties Nd4Ga2O9 and Sm4Ga2O9[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2004,381(1-2):26-31.
APA Liu, FS.,Liu, QL.,Liang, JK.,Song, GB.,Luo, J.,...&Rao, GH.(2004).Crystal structure and magnetic properties Nd4Ga2O9 and Sm4Ga2O9.JOURNAL OF ALLOYS AND COMPOUNDS,381(1-2),26-31.
MLA Liu, FS,et al."Crystal structure and magnetic properties Nd4Ga2O9 and Sm4Ga2O9".JOURNAL OF ALLOYS AND COMPOUNDS 381.1-2(2004):26-31.

入库方式: OAI收割

来源:金属研究所

浏览0
下载0
收藏0
其他版本

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。