中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
MECHANISM OF B IN HYDROGEN-RESISTANCE J75 ALLOY

文献类型:期刊论文

作者Liang Hao2; Zhao Mingjiu1; Chen Shenghu1; Xu Yong2; Wang Yongli1; Rong Lijian1
刊名ACTA METALLURGICA SINICA
出版日期2015-12-11
卷号51期号:12页码:1538-1544
ISSN号0412-1961
关键词J75 alloy B hydrogen-resistant performance eta phase
通讯作者Zhao Mingjiu(mjzhao@imr.ac.cn)
英文摘要With the development of hydrogen economy, the demand of structural materials with high strength suitable for service in hydrogen or hydrogen-bearing environments such as storage of hydrogen gas was incremental. An optional structural materials is J75 alloy, which is mainly strengthened by an ordered fcc gamma' phase, Ni-3(Al, Ti), coherent with the austenite matrix. Investigation on J75 alloy indicated that the commercial alloy free of B would lose about half its ductility when charged with hydrogen, accompanied by a change of fracture mode from ductile rupture to brittle-appearing intergranular fracture. Otherwise, an improvement in ductility and hydrogen resistant performance was observed in the J75 alloy with trace B, however, its role in the alloy is unclear. So, in present work, mechanism of B in the J75 hydrogen-resistant alloy was investigated by means of OM, SEM, TEM, EPMA, 3DAP, SIMS, hydrogen penetration, thermal hydrogen charging experiments and tensile tests. It was found that a lot of Ti segregated at grain boundaries (GBs) in the alloy free of B, resulted in abundant precipitation of cellular eta phases. However, the cellular eta phase was not observed in the alloy with B, and it could be attributed to the segregation of B atoms at GBs and inhibited the segregation of Ti. A lower hydrogen diffusion coefficient was observed in the alloy with B than that in the alloy free of B by hydrogen permeation, indicating that diffusion velocity of H atoms in the alloy had been decreased by the addition of B. Moreover, segregation of B at GBs could not only inhibit the precipitation of eta phases but also decrease the number of H atoms there, which would improve the hydrogen-resistant performance of the alloy.
资助项目National Natural Science Foundation of China and China Academy of Engineering Physics[U1230118] ; National Natural Science Foundation of China[51171178]
WOS研究方向Metallurgy & Metallurgical Engineering
语种英语
出版者SCIENCE PRESS
WOS记录号WOS:000367770600015
资助机构National Natural Science Foundation of China and China Academy of Engineering Physics ; National Natural Science Foundation of China
源URL[http://ir.imr.ac.cn/handle/321006/121497]  
专题金属研究所_中国科学院金属研究所
通讯作者Zhao Mingjiu
作者单位1.Chinese Acad Sci, Inst Met Res, Key Lab Nucl Mat & Safety Assessment, Shenyang 110016, Peoples R China
2.China Acad Engn Phys, Inst Syst Engn, Mianyang 621900, Peoples R China
推荐引用方式
GB/T 7714
Liang Hao,Zhao Mingjiu,Chen Shenghu,et al. MECHANISM OF B IN HYDROGEN-RESISTANCE J75 ALLOY[J]. ACTA METALLURGICA SINICA,2015,51(12):1538-1544.
APA Liang Hao,Zhao Mingjiu,Chen Shenghu,Xu Yong,Wang Yongli,&Rong Lijian.(2015).MECHANISM OF B IN HYDROGEN-RESISTANCE J75 ALLOY.ACTA METALLURGICA SINICA,51(12),1538-1544.
MLA Liang Hao,et al."MECHANISM OF B IN HYDROGEN-RESISTANCE J75 ALLOY".ACTA METALLURGICA SINICA 51.12(2015):1538-1544.

入库方式: OAI收割

来源:金属研究所

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