Study on the crystal structure of (Gd2-xCex)Ti2O7 (0 <= x <= 0.8) pyrochlore
文献类型：期刊论文
| 作者 | Zhang, K. Q.1,2; Liu, C. G.2; Li, F. Z.1; Yang, D. Y.2; Chen, C.1; Wu, R. D.3; Peng, S. M.1; Li, Y. H.2; Zhang, H. B.1 |
| 刊名 | ADVANCES IN APPLIED CERAMICS
 |
| 出版日期 | 2016 |
| 卷号 | 115期号:7页码:411-416 |
| 关键词 | Solution combustion Pyrochlore Crystal structure First-principle calculations Solubility Lattice parameters Rietveld refinement X-ray diffraction analysis |
| ISSN号 | 1743-6753 |
| DOI | 10.1080/17436753.2016.1172167 |
| 通讯作者 | Li, Y. H.(liyuhong@lzu.edu.cn) ; Zhang, H. B.(hbzhang@caep.cn) |
| 英文摘要 | Synthesis, characterisation and crystal structure analysis studies of oxides in (Gd2-xCex)Ti2O7 series have been reported, Ce3+ used as a surrogate for Pu3+ because they have similar physical and chemical properties. In the present report, a series of pyrochlore-type crystal with composition (Gd2-xCex)Ti2O7 (0 <= x <= 0.8) were successfully synthesised by the solution combustion followed by high temperature calcining. The phase purity and crystal structure of samples were investigated by X-ray diffraction analysis as well as Rietveld refinement. It was observed that the solubility of Ce3+ in the lattice of Gd2Ti2O7 pyrochlore is 39.62 mol.-%. The calculated lattice parameters and the simulated XRD patterns of (Gd2-xCex)Ti2O7 (x = 0, 0.5, 1) were obtained based on the density functional theory. The results of theoretical calculation are quite consistent with the results of the experiment. Additionally, the grain size and the visual information about the microscopic structure of the (Gd2-xCex)Ti2O7 crystals were obtained by transmission electron microscopy. |
| 资助项目 | National Natural Science Foundation of China[11175076] ; National Natural Science Foundation of China[11475076] |
| WOS研究方向 | Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000382256300006 |
| 出版者 | TAYLOR & FRANCIS LTD |
| 资助机构 | National Natural Science Foundation of China |
| 源URL | [http://ir.imr.ac.cn/handle/321006/122563]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Li, Y. H.; Zhang, H. B. |
| 作者单位 | 1.China Acad Engn Phys, Inst Nucl Phys & Chem, Mianyang 621900, Peoples R China 2.Lanzhou Univ, Sch Nucl Sci & Technol, Lanzhou 7340000, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, K. Q.,Liu, C. G.,Li, F. Z.,et al. Study on the crystal structure of (Gd2-xCex)Ti2O7 (0 <= x <= 0.8) pyrochlore[J]. ADVANCES IN APPLIED CERAMICS,2016,115(7):411-416. |
| APA | Zhang, K. Q..,Liu, C. G..,Li, F. Z..,Yang, D. Y..,Chen, C..,...&Zhang, H. B..(2016).Study on the crystal structure of (Gd2-xCex)Ti2O7 (0 <= x <= 0.8) pyrochlore.ADVANCES IN APPLIED CERAMICS,115(7),411-416. |
| MLA | Zhang, K. Q.,et al."Study on the crystal structure of (Gd2-xCex)Ti2O7 (0 <= x <= 0.8) pyrochlore".ADVANCES IN APPLIED CERAMICS 115.7(2016):411-416. |
入库方式： OAI收割
来源：金属研究所
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