Rational Design of Zirconium-doped Titania Photocatalysts with Synergistic Bronsted Acidity and Photoactivity
文献类型：期刊论文
| 作者 | Ma, Runyuan1; Wang, Liang1; Zhang, Bingsen2; Yi, Xianfeng3; Zheng, Anmin3; Deng, Feng3; Yan, Xuhua4; Pan, Shuxiang1; Wei, Xiao5; Wang, Kai-Xue5 |
| 刊名 | CHEMSUSCHEM
 |
| 出版日期 | 2016-10-06 |
| 卷号 | 9期号:19页码:2759-2764 |
| 关键词 | heterogeneous catalysis oxidation sulfur titania zirconium |
| ISSN号 | 1864-5631 |
| DOI | 10.1002/cssc.201600812 |
| 通讯作者 | Wang, Liang(liangwang@zju.edu.cn) ; Su, Dang Sheng(dssu@imr.ac.cn) ; Xiao, Feng-Shou(fsxiao@zju.edu.cn) |
| 英文摘要 | The preparation of photocatalysts with high activities under visible-light illumination is challenging. We report the rational design and construction of a zirconium-doped anatase catalyst (S-Zr-TiO2) with Bronsted acidity and photoactivity as an efficient catalyst for the degradation of phenol under visible light. Electron microscopy images demonstrate that the zirconium sites are uniformly distributed on the sub-10 nm anatase crystals. UV-visible spectrometry indicates that the S-Zr-TiO2 is a visible-light-responsive catalyst with narrower band gap than conventional anatase. Pyridine-adsorption infrared and acetone-adsorption C-13 NMR spectra confirm the presence of Bronsted acidic sites on the S-Zr-TiO2 sample. Interestingly, the S-Zr-TiO2 catalyst exhibits high catalytic activity in the degradation of phenol under visible-light illumination, owing to a synergistic effect of the Bronsted acidity and photoactivity. Importantly, the S-Zr-TiO2 shows good recyclability. |
| 资助项目 | National Natural Science Foundation of China[21333009] ; National Natural Science Foundation of China[U1462202] ; National Natural Science Foundation of China[21403192] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000386952000005 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | National Natural Science Foundation of China |
| 源URL | [http://ir.imr.ac.cn/handle/321006/123077]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Wang, Liang; Su, Dang Sheng; Xiao, Feng-Shou |
| 作者单位 | 1.Zhejiang Univ, Key Lab Appl Chem Zhejiang Prov, Hangzhou 310028, Peoples R China 2.Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Shenyang 10016, Peoples R China 3.Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China 4.Zhejiang Univ, Dept Chem Engn, Hangzhou 310027, Peoples R China 5.Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, Shanghai 200240, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ma, Runyuan,Wang, Liang,Zhang, Bingsen,et al. Rational Design of Zirconium-doped Titania Photocatalysts with Synergistic Bronsted Acidity and Photoactivity[J]. CHEMSUSCHEM,2016,9(19):2759-2764. |
| APA | Ma, Runyuan.,Wang, Liang.,Zhang, Bingsen.,Yi, Xianfeng.,Zheng, Anmin.,...&Xiao, Feng-Shou.(2016).Rational Design of Zirconium-doped Titania Photocatalysts with Synergistic Bronsted Acidity and Photoactivity.CHEMSUSCHEM,9(19),2759-2764. |
| MLA | Ma, Runyuan,et al."Rational Design of Zirconium-doped Titania Photocatalysts with Synergistic Bronsted Acidity and Photoactivity".CHEMSUSCHEM 9.19(2016):2759-2764. |
入库方式： OAI收割
来源：金属研究所
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