Conjugated polymers with defined chemical structure as model carbon catalysts for nitro reduction
文献类型：期刊论文
| 作者 | Guo, Xiaoling2,3; Qi, Wei2; Liu, Wei2; Liang, Changhai3; Zheng, Anmin1; Yi, Xianfeng1; Su, Dangsheng2 |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2016 |
| 卷号 | 6期号:101页码:99570-99576 |
| ISSN号 | 2046-2069 |
| DOI | 10.1039/c6ra18201a |
| 通讯作者 | Su, Dangsheng(dssu@imr.ac.cn) |
| 英文摘要 | A series of conjugated polymers (YPB-x) with designated chemical structure are synthesized as model carbon catalysts for mechanistic and kinetic studies of nitroaromatic reduction reactions. The reaction kinetics show that ketonic carbonyl groups are active sites for the nitrobenzene (NB) reduction. A catalytic reaction mechanism involving the activation of hydrazine with carbon catalysts and the subsequent reduction of NB is proposed to describe the catalytic process molecularly. The turnover frequency of heterogeneous carbon catalysts in the liquid phase is reported for the fair comparison of the intrinsic activity among different carbon catalysts. |
| 资助项目 | NSFC of China[21303226] ; NSFC of China[21133010] ; NSFC of China[21573256] ; NSFC of China[51221264] ; NSFC of China[21261160487] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA09030103] ; Youth Innovation Promotion Association of CAS |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000387427800121 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | NSFC of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Youth Innovation Promotion Association of CAS |
| 源URL | [http://ir.imr.ac.cn/handle/321006/123153]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Su, Dangsheng |
| 作者单位 | 1.Chinese Acad Sci, Wuhan Inst Phys & Math, Natl Ctr Magnet Resonance Wuhan, Wuhan 430071, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 3.Dalian Univ Technol, Sch Chem Engn, Lab Adv Mat & Catalyt Engn, Dalian 116024, Peoples R China |
| 推荐引用方式 GB/T 7714 | Guo, Xiaoling,Qi, Wei,Liu, Wei,et al. Conjugated polymers with defined chemical structure as model carbon catalysts for nitro reduction[J]. RSC ADVANCES,2016,6(101):99570-99576. |
| APA | Guo, Xiaoling.,Qi, Wei.,Liu, Wei.,Liang, Changhai.,Zheng, Anmin.,...&Su, Dangsheng.(2016).Conjugated polymers with defined chemical structure as model carbon catalysts for nitro reduction.RSC ADVANCES,6(101),99570-99576. |
| MLA | Guo, Xiaoling,et al."Conjugated polymers with defined chemical structure as model carbon catalysts for nitro reduction".RSC ADVANCES 6.101(2016):99570-99576. |
入库方式： OAI收割
来源：金属研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。