Membrane Permeability Rates of Vanadium Ions and Their Effects on Temperature Variation in Vanadium Redox Batteries
文献类型：期刊论文
| 作者 | Cao, Liuyue1; Kronander, Anders1; Tang, Ao2; Wang, Da-Wei1; Skyllas-Kazacos, Maria1 |
| 刊名 | ENERGIES
 |
| 出版日期 | 2016-12-01 |
| 卷号 | 9期号:12页码:15 |
| 关键词 | permeability rates diffusion crossover ion exchange membrane vanadium redox flow batteries (VRFBs) capacity side reactions |
| ISSN号 | 1996-1073 |
| DOI | 10.3390/en9121058 |
| 通讯作者 | Skyllas-Kazacos, Maria(m.kazacos@unsw.edu.au) |
| 英文摘要 | The inevitable diffusion of vanadium ions across the membrane can cause considerable capacity loss and temperature increase in vanadium redox flow batteries (VRFBs) over long term operation. Reliable experimental data of the permeability rates of vanadium ions are needed for membrane selection and for use in mathematical models to predict long-term behavior. In this paper a number of ion exchange membranes were selected for detailed evaluation using a modified approach to obtain more accurate permeation rates of V2+, V3+, VO2+ and VO2+ ions. Three commercial ion exchange membranes-FAP450, VB2 and F930-are investigated. The obtained diffusion coefficients are then employed in dynamic models to predict the thermal behavior under specific operating conditions. The simulation results prove that smaller and more balanced permeability rates of V2+ and VO2+ ions are more important to avoid large temperature increases in the cell stack during stand-by periods at high states-of-charge with pumps off. |
| 资助项目 | Faculty of Engineering, UNSW ; University International Postgraduate Award Scholarship |
| WOS研究方向 | Energy & Fuels |
| 语种 | 英语 |
| WOS记录号 | WOS:000392402700059 |
| 出版者 | MDPI AG |
| 资助机构 | Faculty of Engineering, UNSW ; University International Postgraduate Award Scholarship |
| 源URL | [http://ir.imr.ac.cn/handle/321006/123662]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Skyllas-Kazacos, Maria |
| 作者单位 | 1.Univ New South Wales, Sch Chem Engn, Sydney, NSW 2052, Australia 2.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cao, Liuyue,Kronander, Anders,Tang, Ao,et al. Membrane Permeability Rates of Vanadium Ions and Their Effects on Temperature Variation in Vanadium Redox Batteries[J]. ENERGIES,2016,9(12):15. |
| APA | Cao, Liuyue,Kronander, Anders,Tang, Ao,Wang, Da-Wei,&Skyllas-Kazacos, Maria.(2016).Membrane Permeability Rates of Vanadium Ions and Their Effects on Temperature Variation in Vanadium Redox Batteries.ENERGIES,9(12),15. |
| MLA | Cao, Liuyue,et al."Membrane Permeability Rates of Vanadium Ions and Their Effects on Temperature Variation in Vanadium Redox Batteries".ENERGIES 9.12(2016):15. |
入库方式： OAI收割
来源：金属研究所
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