Highly efficient catalysts of chitosan-Schiff base Co(II) and Pd(II) complexes for aerobic oxidation of cyclohexane in the absence of reductants and solvents
文献类型：期刊论文
| 作者 | Tong, JH; Zhen, L; Xia, CG |
| 刊名 | JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
 |
| 出版日期 | 2005-04-20 |
| 卷号 | 231期号:1-2页码:197-203 |
| 关键词 | chitosan-Schiff base Co(II) and Pd(II) complexes oxygen cyclohexane oxidation |
| ISSN号 | 1381-1169 |
| DOI | 10.1016/j.molcata.2005.01.011 |
| 通讯作者 | Xia, CG() |
| 英文摘要 | Three chitosan-Schiff base Co(II) and Pd(II) complexes were prepared in a simple way and characterized by FT-IR, XPS and TG. Their abilities to catalyze oxidation of cyclohexane into cyclohexanone and cyclohexanol with oxygen in the absence of any solvents or reducing agents were studied. It has been revealed that the complexes had high catalytic activities for heterogeneous cyclohexane oxidation with oxygen. Especially, the oxidation of cyclohexane catalyzed by chitosan-salicyaldehyde Schiff base Co(II) complex under 1.6MPa of initial oxygen pressure at 418 K gave excellent results with 9100 turnover numbers (based on the cobalt atom) and 96% selectivity for cyclohexanone and cyclohexanol after reaction of 4.5 h. The influences of oxygen pressure, reaction temperature and reaction time on the oxidation of cyclohexane were also investigated. It has been also revealed that the complexes were efficient for the oxidation of bulky cyclic alkanes and linear alkanes. (c) 2005 Elsevier B.V. All rights reserved. |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000227966600024 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.imr.ac.cn/handle/321006/126103]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Xia, CG |
| 作者单位 | 1.Chinese Acad Sci, Labzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Grad Sch Chinese Acad Sci, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tong, JH,Zhen, L,Xia, CG. Highly efficient catalysts of chitosan-Schiff base Co(II) and Pd(II) complexes for aerobic oxidation of cyclohexane in the absence of reductants and solvents[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2005,231(1-2):197-203. |
| APA | Tong, JH,Zhen, L,&Xia, CG.(2005).Highly efficient catalysts of chitosan-Schiff base Co(II) and Pd(II) complexes for aerobic oxidation of cyclohexane in the absence of reductants and solvents.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,231(1-2),197-203. |
| MLA | Tong, JH,et al."Highly efficient catalysts of chitosan-Schiff base Co(II) and Pd(II) complexes for aerobic oxidation of cyclohexane in the absence of reductants and solvents".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 231.1-2(2005):197-203. |
入库方式： OAI收割
来源：金属研究所
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