Synthesis and crystal structure of [Cu(4-OOCC6H4CN)(2) (4-HOOCC6H4CN)(H2O)(2)] center dot 2(4-HOOCC6H4CN): a hydrogen bonded assembly of the first transition metal complex of 4-cyanobenzoic acid
文献类型：期刊论文
| 作者 | Wang, MS; Cai, LZ; Zhou, GW; Guo, GC; Huang, JS |
| 刊名 | INORGANIC CHEMISTRY COMMUNICATIONS
 |
| 出版日期 | 2003-07-01 |
| 卷号 | 6期号:7页码:855-858 |
| 关键词 | 4-cyanobenzoic acid Cu(II) complex hydrogen bonding carboxylic dimer synthon |
| ISSN号 | 1387-7003 |
| DOI | 10.1016/S1387-7003(03)00121-7 |
| 通讯作者 | Guo, GC() |
| 英文摘要 | The first transition metal complex of 4-cyanobenzoic acid, [Cu(4-OOCC6H4CN)(2)(4-HOOCC6H4CN)(H2O)(2)]. 2(4-HOOCC6H4CN), has been prepared in aqueous medium. X-ray single crystal structure analysis reveals that it is a monometallic complex. Five-coordination Cu(II) ion is approximately in a square based pyramidal environment. Three-dimensional network of this compound is formed through O-H...N, O-H...O, C-H...O and C-H...N hydrogen bonding interactions, yielding a grid framework containing dimers of 4-cyanobenzoic acid with carboxylic dimer 2synthons locating in the channels. (C) 2003 Elsevier Science B.V. All rights reserved. |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000183745800016 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.imr.ac.cn/handle/321006/126927]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Guo, GC |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China 2.Grad Sch Chinese Acad Sci, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, MS,Cai, LZ,Zhou, GW,et al. Synthesis and crystal structure of [Cu(4-OOCC6H4CN)(2) (4-HOOCC6H4CN)(H2O)(2)] center dot 2(4-HOOCC6H4CN): a hydrogen bonded assembly of the first transition metal complex of 4-cyanobenzoic acid[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2003,6(7):855-858. |
| APA | Wang, MS,Cai, LZ,Zhou, GW,Guo, GC,&Huang, JS.(2003).Synthesis and crystal structure of [Cu(4-OOCC6H4CN)(2) (4-HOOCC6H4CN)(H2O)(2)] center dot 2(4-HOOCC6H4CN): a hydrogen bonded assembly of the first transition metal complex of 4-cyanobenzoic acid.INORGANIC CHEMISTRY COMMUNICATIONS,6(7),855-858. |
| MLA | Wang, MS,et al."Synthesis and crystal structure of [Cu(4-OOCC6H4CN)(2) (4-HOOCC6H4CN)(H2O)(2)] center dot 2(4-HOOCC6H4CN): a hydrogen bonded assembly of the first transition metal complex of 4-cyanobenzoic acid".INORGANIC CHEMISTRY COMMUNICATIONS 6.7(2003):855-858. |
入库方式： OAI收割
来源：金属研究所
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