Ti3C2Tx MXene Catalyzed Ethylbenzene Dehydrogenation: Active Sites and Mechanism Exploration from both Experimental and Theoretical Aspects
文献类型：期刊论文
| 作者 | Diao, Jiangyong1; Hu, Minmin1,2; Lian, Zan1,2; Li, Zhaojin1; Zhang, Hui1; Huang, Fei1,2; Li, Bo1; Wang, Xiaohui1; Su, Dang Sheng1; Liu, Hongyang1 |
| 刊名 | ACS CATALYSIS
 |
| 出版日期 | 2018-11-01 |
| 卷号 | 8期号:11页码:10051-10057 |
| 关键词 | MXene direct dehydrogenation ethylbenzene styrene heterogeneous catalysis |
| ISSN号 | 2155-5435 |
| DOI | 10.1021/acscatal.8b02002 |
| 通讯作者 | Li, Bo(boli@imr.ac.cn) ; Wang, Xiaohui(wang@imr.ac.cn) ; Liu, Hongyang(liuhy@imr.ac.cn) |
| 英文摘要 | Two-dimensional materials (such as graphene, MXenes) usually perform remarkably well as catalysts in comparison with their three-dimensional counterparts. In this work, Ti3AlC2-derived Ti3C2Tx MXene (T = O, OH, F) was prepared and employed in the direct dehydrogenation of ethylbenzene. A 92 mu mol m(-2) h(-1) reactivity and a 40 h stability with almost no deactivation were observed, which is much better than those of the previously reported nanocarbon catalysts. The graphene-like layered structure and the C-Ti-O termination groups induced by the preparation process were thought to account for the good catalytic performance of Ti3C2Tx MXene from both experimental and computational perspectives. The discovery expands the application of two-dimensional MXenes and provides more choices in exploring high activity catalysts for hydrocarbon dehydrogenation reactions. |
| 资助项目 | Ministry of Science and Technology[2016YFA0204100] ; National Natural Science Foundation of China[21703261] ; National Natural Science Foundation of China[21573254] ; National Natural Science Foundation of China[91545110] ; Institute of Metal Research, Youth Innovation Promotion Association (CAS) ; Sinopec China ; Shenyang National Laboratory for Materials Science[18LHPY010] ; State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals[18LHPY010] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000449723900016 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | Ministry of Science and Technology ; National Natural Science Foundation of China ; Institute of Metal Research, Youth Innovation Promotion Association (CAS) ; Sinopec China ; Shenyang National Laboratory for Materials Science ; State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals |
| 源URL | [http://ir.imr.ac.cn/handle/321006/130274]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Li, Bo; Wang, Xiaohui; Liu, Hongyang |
| 作者单位 | 1.Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, 96 Jinzhai Rd, Hefei 230026, Anhui, Peoples R China |
| 推荐引用方式 GB/T 7714 | Diao, Jiangyong,Hu, Minmin,Lian, Zan,et al. Ti3C2Tx MXene Catalyzed Ethylbenzene Dehydrogenation: Active Sites and Mechanism Exploration from both Experimental and Theoretical Aspects[J]. ACS CATALYSIS,2018,8(11):10051-10057. |
| APA | Diao, Jiangyong.,Hu, Minmin.,Lian, Zan.,Li, Zhaojin.,Zhang, Hui.,...&Liu, Hongyang.(2018).Ti3C2Tx MXene Catalyzed Ethylbenzene Dehydrogenation: Active Sites and Mechanism Exploration from both Experimental and Theoretical Aspects.ACS CATALYSIS,8(11),10051-10057. |
| MLA | Diao, Jiangyong,et al."Ti3C2Tx MXene Catalyzed Ethylbenzene Dehydrogenation: Active Sites and Mechanism Exploration from both Experimental and Theoretical Aspects".ACS CATALYSIS 8.11(2018):10051-10057. |
入库方式： OAI收割
来源：金属研究所
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