Hybrid graphene album with polysulfides adsorption layer for Li-S batteries
文献类型：期刊论文
| 作者 | Hong, Xiaodong1,2; Liang, Ji2; Tang, Xiaonan2,3; Yang, Huicong2; Li, Feng2 |
| 刊名 | CHEMICAL ENGINEERING SCIENCE
 |
| 出版日期 | 2019-02-02 |
| 卷号 | 194页码:148-155 |
| 关键词 | Graphitic carbon nitride Graphene album Self-assembly Lithium-sulfur battery |
| ISSN号 | 0009-2509 |
| DOI | 10.1016/j.ces.2018.03.027 |
| 通讯作者 | Li, Feng(fli@imr.ac.cn) |
| 英文摘要 | Lithium-sulfur (Li-S) battery is a promising candidate for the next-generation power sources due to their low-cost and high energy density. However, the shuttle effect of the dissolved polysulfides in the electrolyte solvents has hindered the commercialization of Li-S batteries. In order to effectively suppress the shuttle effect, we design and prepare a bybrid graphene album structure as an efficient polysulfides-trapped host for Li-S battery. In this composite, the graphene album structure is stacked by graphene layer by layer through a bottom-up assembly, which provides a hierarchical porous structure, easy mass transport and excellent conductivity for the cathode host of Li-S batteries. The uniform g-C3N4 layer was in-situ generated on each graphene by hydrothermal treatment and heat polycondensation. The orderly bybrid graphene album (coded as g-C3N4@n-G) achieves the two-dimensional surface adsorption interaction for imobilizing soluble polysulfides, and the multilayer barriers also effectively prevent the escape of polysulfides to enhance the long cycling stability of Li-S batteries. As a result, an extremely low capacity decay of 0.028% cycle(-1) and a high initial capacity of 1252 mA h g(-1) have been achieved at 0.2 C. Furthermore, this kind of unique design and preparation method for hybrid graphene album also opens an opportunity for the construction of other album-like graphene-based hybrids. (C) 2018 Elsevier Ltd. All rights reserved. |
| 资助项目 | Ministry of Science and Technology of China[2016YFA0200100] ; Ministry of Science and Technology of China[2016YFB0100100] ; Ministry of Science and Technology of China[2014CB932402] ; Natural Science Foundation of China[51525206] ; Natural Science Foundation of China[51521091] ; Natural Science Foundation of China[51372253] ; Natural Science Foundation of China[51403094] ; Natural Science Foundation of China[U1401243] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA09010104] ; Key Research Program of the Chinese Academy of Sciences[KGZD-EW-T06] ; CAS/SAFEA International Partnership Program for Creative Research Teams |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000451917900020 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 资助机构 | Ministry of Science and Technology of China ; Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; CAS/SAFEA International Partnership Program for Creative Research Teams |
| 源URL | [http://ir.imr.ac.cn/handle/321006/130506]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Li, Feng |
| 作者单位 | 1.Liaoning Tech Univ, Coll Mat Sci & Engn, Fuxing 123000, Peoples R China 2.Chinese Acad Sci, Inst Met Res, 72 Wenhua Rd, Shenyang 110016, Peoples R China 3.Shandong Univ Technol, Sch Chem Engn, Zibo 255000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hong, Xiaodong,Liang, Ji,Tang, Xiaonan,et al. Hybrid graphene album with polysulfides adsorption layer for Li-S batteries[J]. CHEMICAL ENGINEERING SCIENCE,2019,194:148-155. |
| APA | Hong, Xiaodong,Liang, Ji,Tang, Xiaonan,Yang, Huicong,&Li, Feng.(2019).Hybrid graphene album with polysulfides adsorption layer for Li-S batteries.CHEMICAL ENGINEERING SCIENCE,194,148-155. |
| MLA | Hong, Xiaodong,et al."Hybrid graphene album with polysulfides adsorption layer for Li-S batteries".CHEMICAL ENGINEERING SCIENCE 194(2019):148-155. |
入库方式： OAI收割
来源：金属研究所
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