Organic-Inorganic Hybrid (beta-Fe3Se4)(4)[Fe(teta)(1.5)] (teta = triethylenetetramine) Nanoplates: Solution Synthesis and Magnetic Properties
文献类型：期刊论文
| 作者 | Pan, Desheng1; Li, Yong1; Han, Zheng1; Li, Bing1; Wang, Chinwei2; Yang, Teng1; Li, Da1; Choi, Chuljin3; Zhang, Zhidong1 |
| 刊名 | CHEMISTRY OF MATERIALS
 |
| 出版日期 | 2018-12-25 |
| 卷号 | 30期号:24页码:8975-8982 |
| ISSN号 | 0897-4756 |
| DOI | 10.1021/acs.chemmater.8b04814 |
| 通讯作者 | Li, Da(dali@imr.ac.cn) |
| 英文摘要 | Incorporation of distinct organic molecules and inorganic fragments into a single crystalline lattice of organic-inorganic hybrid magnets has aroused much attention for novel physical properties and applications. Yet, there has been no report on the discovery of ordered organic-inorganic hybrid magnets with room-temperature magnetism. Here, we report a simple chemical solution method for synthesis of new organic-inorganic hybrid magnets built by organic Fe(teta)(1.5) and inorganic FeSex segments. By changing the reaction temperature, the size of these hybrid nanostructures can be tuned from 100 nm to 4 mu m, and their shapes vary from nanoparticles and nanobelts to nanoplates. Selected area electron diffraction and X-ray diffraction reveal that hybrid (beta-Fe3Se4)(4)[Fe(teta)(1.5)] nanoplates are a single phase in a tetragonal crystal structure with the space group I4cm (108). The thermal magnetic curve between 5 and 900 K was characterized using a vibrating sample magnetometer, revealing room-temperature ferrimagnetism of the (beta-Fe3Se4)(4)[Fe(teta)(1.5)] nanoplates with the Curie temperature (T-C) higher than 530 K. In the case of hybrid nanoplates synthesized at 483 K, a giant coercivity value reaching 11 kOe is obtained at 5 K. Our study not only provides guidance for developing a chemical solution method for controllable fabrication of a new class of organic-inorganic hybrid materials but also enhances the magnetic ordering temperature of such magnetic organic-inorganic hybrid materials to be higher than room temperature. |
| 资助项目 | ministry of Science and Technology of China[2017YFA0206302] ; ministry of Science and Technology of China[2017YFA0700702] ; National Natural Science Foundation of China[51371175] ; National Natural Science Foundation of China[51331006] ; National Research Foundation of Korea (NRF) - Ministry of Science and technology and ICT[2016M3D1A1027835] |
| WOS研究方向 | Chemistry ; Materials Science |
| 语种 | 英语 |
| 出版者 | AMER CHEMICAL SOC |
| WOS记录号 | WOS:000454567100032 |
| 资助机构 | ministry of Science and Technology of China ; National Natural Science Foundation of China ; National Research Foundation of Korea (NRF) - Ministry of Science and technology and ICT |
| 源URL | [http://ir.imr.ac.cn/handle/321006/130967]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Li, Da |
| 作者单位 | 1.Univ Sci & Technol China, Chinese Acad Sci, Sch Mat Sci & Engn, Shenyang Natl Lab Mat Sci,Inst Met Res, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China 2.Natl Synchrotron Radiat Res Ctr, Hsinchu 30076, Taiwan 3.Korea Inst Mat Sci, 797 Changwondaero, Chang Won 51508, Gyeongnam, South Korea |
| 推荐引用方式 GB/T 7714 | Pan, Desheng,Li, Yong,Han, Zheng,et al. Organic-Inorganic Hybrid (beta-Fe3Se4)(4)[Fe(teta)(1.5)] (teta = triethylenetetramine) Nanoplates: Solution Synthesis and Magnetic Properties[J]. CHEMISTRY OF MATERIALS,2018,30(24):8975-8982. |
| APA | Pan, Desheng.,Li, Yong.,Han, Zheng.,Li, Bing.,Wang, Chinwei.,...&Zhang, Zhidong.(2018).Organic-Inorganic Hybrid (beta-Fe3Se4)(4)[Fe(teta)(1.5)] (teta = triethylenetetramine) Nanoplates: Solution Synthesis and Magnetic Properties.CHEMISTRY OF MATERIALS,30(24),8975-8982. |
| MLA | Pan, Desheng,et al."Organic-Inorganic Hybrid (beta-Fe3Se4)(4)[Fe(teta)(1.5)] (teta = triethylenetetramine) Nanoplates: Solution Synthesis and Magnetic Properties".CHEMISTRY OF MATERIALS 30.24(2018):8975-8982. |
入库方式： OAI收割
来源：金属研究所
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