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Superhydrophobicity, conductivity and anticorrosion of robust siloxane-acrylic coatings modified with graphene nanosheets

文献类型:期刊论文

作者Uzoma, Paul C.1,2,3; Liu, Fuchun1,2; Xu, Long1,2; Zhang, Zhichao1,2; Han, En-Hou1,2; Ke, Wei1,2; Arukalam, I. O.3
刊名PROGRESS IN ORGANIC COATINGS
出版日期2019-02-01
卷号127页码:239-251
关键词Superhydrophobic Graphene Organic coatings Aluminum Anticorrosion
ISSN号0300-9440
DOI10.1016/j.porgcoat.2018.11.018
通讯作者Liu, Fuchun(fcliu@imr.ac.cn)
英文摘要The effects of low-cost graphene nanosheets in organic coatings were investigated. The hydrophobic organic siloxane-acrylic resin was synthesized by solution polymerization of acrylic monomers while the graphene nanosheets were modified using fluorosilane, and applied on LY12 aluminum substrate via spraying and a two-step coating system. The superhydrophobic, conductive, anticorrosion, self-cleaning, oleophilic and physical behaviors were comprehensively characterized. The results obtained revealed that addition of modified graphene increases the surface conductivity >= 2 mu S/cm) and the water contact angle >= 152 degrees) with low sliding angle (<= 7 degrees). The polarization measurement showed a positive shift in the corrosion potential signifying an inhibition of the cathodic reaction. Also, the two-step coated sample gave a good corrosion protection barrier as further confirmed by the electrochemical impedance parameters. The coating revealed good resistance to dirt adhesion, and its superhydrophobic-oleophilic property offered a promising application in oil-water separation. The physical integrity of the coatings was not extensively affected including after 120 days of outdoor exposure to snowing, de-freezing and surface wetting.
资助项目Special Scientific Research on Civil Aircraft[MJ-2016-F-07]
WOS研究方向Chemistry ; Materials Science
语种英语
WOS记录号WOS:000456755300026
出版者ELSEVIER SCIENCE SA
资助机构Special Scientific Research on Civil Aircraft
源URL[http://ir.imr.ac.cn/handle/321006/131696]  
专题金属研究所_中国科学院金属研究所
通讯作者Liu, Fuchun
作者单位1.Chinese Acad Sci, Key Lab Nucl Mat & Safety Assessment, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China
2.Univ Sci & Technol China, 96 Jin Zhai Rd, Hefei 230026, Anhui, Peoples R China
3.Fed Univ Technol Owerri, Dept Polymer & Text Engn, PMB 1526, Owerri, Nigeria
推荐引用方式
GB/T 7714
Uzoma, Paul C.,Liu, Fuchun,Xu, Long,et al. Superhydrophobicity, conductivity and anticorrosion of robust siloxane-acrylic coatings modified with graphene nanosheets[J]. PROGRESS IN ORGANIC COATINGS,2019,127:239-251.
APA Uzoma, Paul C..,Liu, Fuchun.,Xu, Long.,Zhang, Zhichao.,Han, En-Hou.,...&Arukalam, I. O..(2019).Superhydrophobicity, conductivity and anticorrosion of robust siloxane-acrylic coatings modified with graphene nanosheets.PROGRESS IN ORGANIC COATINGS,127,239-251.
MLA Uzoma, Paul C.,et al."Superhydrophobicity, conductivity and anticorrosion of robust siloxane-acrylic coatings modified with graphene nanosheets".PROGRESS IN ORGANIC COATINGS 127(2019):239-251.

入库方式: OAI收割

来源:金属研究所

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