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Chinese Academy of Sciences Institutional Repositories Grid
Achieving Ultrahigh Hardness in Electrodeposited Nanograined Ni-Based Binary Alloys

文献类型:期刊论文

作者Zheng, Xiangui2; Hu, Jian1,2; Li, Jiongxian2; Shi, Yinong2
刊名NANOMATERIALS
出版日期2019-04-01
卷号9期号:4页码:11
ISSN号2079-4991
关键词electrodeposition nanograined alloy thermal stability annealing hardening hardness
DOI10.3390/nano9040546
通讯作者Shi, Yinong(yinongshi@imr.ac.cn)
英文摘要Annealing hardening has recently been found in nanograined (ng) metals and alloys, which is ascribed to the promotion of grain boundary (GB) stability through GB relaxation and solute atom GB segregation. Annealing hardening is of great significance in extremely fine ng metals since it allows the hardness to keep increasing with a decreasing grain size which would otherwise be softened. Consequently, to synthesize extremely fine ng metals with a stable structure is crucial in achieving an ultrahigh hardness in ng metals. In the present work, direct current electrodeposition was employed to synthesize extremely fine ng Ni-Mo and Ni-P alloys with a grain size of down to a few nanometers. It is demonstrated that the grain size of the as-synthesized extremely fine ng Ni-Mo and Ni-P alloys can be as small as about 3 nm with a homogeneous structure and chemical composition. Grain size strongly depends upon the content of solute atoms (Mo and P). Most importantly, appropriate annealing induces significant hardening as high as 11 GPa in both ng Ni-Mo and Ni-P alloys, while the peak hardening temperature achieved in ng Ni-Mo is much higher than that in ng Ni-P. Electrodeposition is efficient in the synthesis of ultrahard bulk metals or coatings.
资助项目Ministry of Science & Technology of China[2017YFA0204401] ; National Science Foundation of China[51231006] ; National Science Foundation of China[ZDYZD201701] ; Shenyang National Laboratory for Materials Science[2016RP05]
WOS研究方向Science & Technology - Other Topics ; Materials Science
语种英语
出版者MDPI
WOS记录号WOS:000467768800062
资助机构Ministry of Science & Technology of China ; National Science Foundation of China ; Shenyang National Laboratory for Materials Science
源URL[http://ir.imr.ac.cn/handle/321006/133367]  
专题金属研究所_中国科学院金属研究所
通讯作者Shi, Yinong
作者单位1.East China Jiaotong Univ, Sch Mat Sci & Engn, Nanchang 330013, Jiangxi, Peoples R China
2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China
推荐引用方式
GB/T 7714
Zheng, Xiangui,Hu, Jian,Li, Jiongxian,et al. Achieving Ultrahigh Hardness in Electrodeposited Nanograined Ni-Based Binary Alloys[J]. NANOMATERIALS,2019,9(4):11.
APA Zheng, Xiangui,Hu, Jian,Li, Jiongxian,&Shi, Yinong.(2019).Achieving Ultrahigh Hardness in Electrodeposited Nanograined Ni-Based Binary Alloys.NANOMATERIALS,9(4),11.
MLA Zheng, Xiangui,et al."Achieving Ultrahigh Hardness in Electrodeposited Nanograined Ni-Based Binary Alloys".NANOMATERIALS 9.4(2019):11.

入库方式: OAI收割

来源:金属研究所

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