Three-Dimensional High-Entropy Alloy-Polymer Composite Nanolattices That Overcome the Strength-Recoverability Trade-off
文献类型：期刊论文
| 作者 | Zhang, Xuan2; Yao, Jiahao3; Liu, Bin2; Yang, Jun4; Lu, Lei3; Li, Yi3; Gao, Huajian1; Li, Xiaoyan2 |
| 刊名 | NANO LETTERS
 |
| 出版日期 | 2018-07-01 |
| 卷号 | 18期号:7页码:4247-4256 |
| 关键词 | nanolattice high-entropy alloy-polymer composite strength recoverability |
| ISSN号 | 1530-6984 |
| DOI | 10.1021/acs.nanolett.8b01241 |
| 通讯作者 | Yao, Jiahao(jhyao@imr.ac.cn) ; Li, Yi(liyi@imr.ac.cn) ; Gao, Huajian(huajian_gao@brown.edu) ; Li, Xiaoyan(xiaoyanlithu@tsinghua.edu.cn) |
| 英文摘要 | Mechanical metamaterials with three-dimensional micro- and nanoarchitectures exhibit unique mechanical properties, such as high specific modulus, specific strength, and energy absorption. However, a conflict exists between strength and recoverability in nearly all the mechanical metamaterials reported recently, in particular the architected micro/nanolattices, which restricts the applications of these materials in energy storage/absorption and mechanical actuation. Here, we demonstrated the fabrication of three-dimensional architected composite nanolattices that overcome the strength-recoverability trade-off. The nanolattices under study are made up of a high-entropy alloy-coated (14.2-126.1 nm in thickness) polymer strut (approximately 260 nm in the characteristic size) fabricated via two-photon lithography and magnetron sputtering deposition. In situ uniaxial compression inside a scanning electron microscope showed that these composite nanolattices exhibit a high specific strength of 0.027 MPa/kg m(3), an ultrahigh energy absorption per unit volume of 4.0 MJ/m(3), and nearly complete recovery after compression under strains exceeding 50%, thus overcoming the traditional strength-recoverability trade-off. During multiple compression cycles, the composite nanolattices exhibit a high energy loss coefficient (converged value after multiple cycles) of 0.5-0.6 at a compressive strain beyond 50%, surpassing the coefficients of all the micro/nanolattices fabricated recently. Our experiments also revealed that, for a given unit cell size, the composite nanolattices coated with a high entropy alloy with thickness in the range of 14-50 nm have the optimal specific modulus, specific strength, and energy absorption per unit volume, which is related to a transition of the dominant deformation mechanism from local buckling to brittle fracture of the struts. |
| 资助项目 | National Natural Science Foundation of China[11522218] ; National Natural Science Foundation of China[11720101002] ; National Natural Science Foundation of China[11372152] ; National Natural Science Foundation of China[51420105001] ; National Basic Research of China[2015CB932500] ; National Science Foundation[DMR-1709318] ; Chinese 1000-talents Plan for Young Researchers |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000439008300028 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Natural Science Foundation of China ; National Basic Research of China ; National Science Foundation ; Chinese 1000-talents Plan for Young Researchers |
| 源URL | [http://ir.imr.ac.cn/handle/321006/135881]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Yao, Jiahao; Li, Yi; Gao, Huajian; Li, Xiaoyan |
| 作者单位 | 1.Brown Univ, Sch Engn, Providence, RI 02912 USA 2.Tsinghua Univ, Dept Engn Mech, Appl Mech Lab, Ctr Adv Mech & Mat, Beijing 100084, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China 4.Dalian Univ Technol, Dept Engn Mech, State Key Lab Struct Anal Ind Equipment, Dalian 116024, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Xuan,Yao, Jiahao,Liu, Bin,et al. Three-Dimensional High-Entropy Alloy-Polymer Composite Nanolattices That Overcome the Strength-Recoverability Trade-off[J]. NANO LETTERS,2018,18(7):4247-4256. |
| APA | Zhang, Xuan.,Yao, Jiahao.,Liu, Bin.,Yang, Jun.,Lu, Lei.,...&Li, Xiaoyan.(2018).Three-Dimensional High-Entropy Alloy-Polymer Composite Nanolattices That Overcome the Strength-Recoverability Trade-off.NANO LETTERS,18(7),4247-4256. |
| MLA | Zhang, Xuan,et al."Three-Dimensional High-Entropy Alloy-Polymer Composite Nanolattices That Overcome the Strength-Recoverability Trade-off".NANO LETTERS 18.7(2018):4247-4256. |
入库方式： OAI收割
来源：金属研究所
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