High-Valence Nickel Single-Atom Catalysts Coordinated to Oxygen Sites for Extraordinarily Activating Oxygen Evolution Reaction
文献类型：期刊论文
| 作者 | Li, Yaguang1,2; Wu, Zhong-Shuai1; Lu, Pengfei1; Wang, Xiao1,3; Liu, Wei1; Liu, Zhibo4; Ma, Jingyuan5; Ren, Wencai4; Jiang, Zheng5; Bao, Xinhe1,6 |
| 刊名 | ADVANCED SCIENCE
 |
| 出版日期 | 2020-01-20 |
| 卷号 | 7期号:5页码:8 |
| 关键词 | high valence nickel oxygen coordination oxygen evolution reaction single-atom catalysts |
| DOI | 10.1002/advs.201903089 |
| 通讯作者 | Wu, Zhong-Shuai(wuzs@dicp.ac.cn) ; Jiang, Zheng(jiangzheng@sinap.ac.cn) |
| 英文摘要 | Single-atom catalysts (SACs) are efficient for maximizing electrocatalytic activity, but have unsatisfactory activity for the oxygen evolution reaction (OER). Herein, the NaCl template synthesis of individual nickel (Ni) SACs is reported, bonded to oxygen sites on graphene-like carbon (denoted as Ni-O-G SACs) with superior activity and stability for OER. A variety of characterizations unveil that the Ni-O-G SACs present 3D porous framework constructed by ultrathin graphene sheets, single Ni atoms, coordinating nickel atoms to oxygen. Consequently, the catalysts are active and robust for OER with extremely low overpotential of 224 mV at current density of 10 mA cm(-2), 42 mV dec(-1) Tafel slope, oxygen production turn over frequency of 1.44 S-1 at 300 mV, and long-term durability without significant degradation for 50 h at exceptionally high current of 115 mA cm(-1), outperforming the state-of-the-art OER SACs. A theoretical simulation further reveals that the bonding between single nickel and oxygen sites results in the extraordinary boosting of OER performance of Ni-O-G SACs. Therefore, this work opens numerous opportunities for creating unconventional SACs via metal-oxygen bonding. |
| 资助项目 | National Key R&D Program of China[2016YFB0100100] ; National Key R&D Program of China[2016YFA0200200] ; National Nature Science Foundation of China[51702078] ; National Nature Science Foundation of China[51572259] ; National Nature Science Foundation of China[51872283] ; Liao Ning Revitalization Talents Program[XLYC1807153] ; Natural Science Foundation of Liaoning Province[20180510038] ; DICP[DICP ZZBS201708] ; DICP[DICP ZZBS201802] ; DICPQIBEBT[DICPQIBEBT UN201702] ; Dalian National Laboratory For Clean Energy (DNL), CAS ; DNL Cooperation Fund, CAS[DNL180310] ; DNL Cooperation Fund, CAS[DNL180308] ; Outstanding Youth Foundation of Hebei Province[A2016201176] ; China Postdoctoral Science Foundation[2018M640262] ; Outstanding Doctoral Cultivation Project of Hebei University[YB201502] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000507977100001 |
| 出版者 | WILEY |
| 资助机构 | National Key R&D Program of China ; National Nature Science Foundation of China ; Liao Ning Revitalization Talents Program ; Natural Science Foundation of Liaoning Province ; DICP ; DICPQIBEBT ; Dalian National Laboratory For Clean Energy (DNL), CAS ; DNL Cooperation Fund, CAS ; Outstanding Youth Foundation of Hebei Province ; China Postdoctoral Science Foundation ; Outstanding Doctoral Cultivation Project of Hebei University |
| 源URL | [http://ir.imr.ac.cn/handle/321006/136786]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Wu, Zhong-Shuai; Jiang, Zheng |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Peoples R China 2.Hebei Univ, Coll Phys Sci & Technol, Hebei Key Lab Opt Informat & Mat, Baoding 071002, Peoples R China 3.Univ Chinese Acad Sci, 19 A Yuquan Rd, Beijing 100049, Peoples R China 4.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 5.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201204, Peoples R China 6.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Yaguang,Wu, Zhong-Shuai,Lu, Pengfei,et al. High-Valence Nickel Single-Atom Catalysts Coordinated to Oxygen Sites for Extraordinarily Activating Oxygen Evolution Reaction[J]. ADVANCED SCIENCE,2020,7(5):8. |
| APA | Li, Yaguang.,Wu, Zhong-Shuai.,Lu, Pengfei.,Wang, Xiao.,Liu, Wei.,...&Bao, Xinhe.(2020).High-Valence Nickel Single-Atom Catalysts Coordinated to Oxygen Sites for Extraordinarily Activating Oxygen Evolution Reaction.ADVANCED SCIENCE,7(5),8. |
| MLA | Li, Yaguang,et al."High-Valence Nickel Single-Atom Catalysts Coordinated to Oxygen Sites for Extraordinarily Activating Oxygen Evolution Reaction".ADVANCED SCIENCE 7.5(2020):8. |
入库方式： OAI收割
来源：金属研究所
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