中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
The effect of Pt nanoparticles distribution on the removal of cyanide by TiO2 coated Al-MCM-41 in blue light exposure

文献类型:期刊论文

作者Kadi, Mohammad W.2; Hameed, A.1,3; Mohamed, R. M.2; Ismail, Iqbal M. I.2,3; Alangari, Yaser2; Cheng, Hui-Ming2,4
刊名ARABIAN JOURNAL OF CHEMISTRY
出版日期2019-11-01
卷号12期号:7页码:957-965
关键词Al-MCM-41 Rice Husk Pt loading TiO2 loaded Al-MCM-41 Cyanide
ISSN号1878-5352
DOI10.1016/j.arabjc.2016.02.001
通讯作者Ismail, Iqbal M. I.(Iqbal30@hotmail.com)
英文摘要With an aim to enhance the photocatalytic activity, Pt loaded TiO2-Al-MCM-41 catalysts with high surface area were synthesized by a multistep route. The waste of the rice processing, rice husk (RH), was used as the precursor for the extraction of silica. The diffuse reflectance and photoluminescence spectroscopy revealed the extension of the absorption edge in the visible region and exciton trapping nature of the dispersed platinum. The structural analysis was carried out by XRD, whereas X-ray photoelectron spectroscopy identified the chemical states of the components of the synthesized powders. The BET surface area measurements revealed the reduction in the surface area and pore volume with the increasing platinum loading. TEM micrographs showed the uniform distribution of TiO2 and Pt nanoparticles at the surface of Al-MCM-41. The photocatalytic efficiency of the synthesized powders as photocatalysts was obtained for the removal of 100 ppm CN- from aqueous solution in fluorescent blue light exposure. Compared to unsupported TiO2, the Pt-loaded catalysts exhibited substantially high activity for the removal of CN-. A plausible mechanism for the removal of cyanide ions was proposed. The catalysts showed excellent stability and reproducibility in the successive use. (C) 2016 The Authors. Production and hosting by Elsevier B.V.
资助项目King Abdulaziz University, Jeddah[50-130-35-HiCi] ; DSR
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000494954400005
出版者ELSEVIER
资助机构King Abdulaziz University, Jeddah ; DSR
源URL[http://ir.imr.ac.cn/handle/321006/136860]  
专题金属研究所_中国科学院金属研究所
通讯作者Ismail, Iqbal M. I.
作者单位1.Quaid i Azam Univ, Natl Ctr Phys, Islamabad 44000, Pakistan
2.King Abdulaziz Univ, Fac Sci, Dept Chem, POB 80203, Jeddah 21589, Saudi Arabia
3.King Abdulaziz Univ, CEES, Jeddah 21589, Saudi Arabia
4.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China
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Kadi, Mohammad W.,Hameed, A.,Mohamed, R. M.,et al. The effect of Pt nanoparticles distribution on the removal of cyanide by TiO2 coated Al-MCM-41 in blue light exposure[J]. ARABIAN JOURNAL OF CHEMISTRY,2019,12(7):957-965.
APA Kadi, Mohammad W.,Hameed, A.,Mohamed, R. M.,Ismail, Iqbal M. I.,Alangari, Yaser,&Cheng, Hui-Ming.(2019).The effect of Pt nanoparticles distribution on the removal of cyanide by TiO2 coated Al-MCM-41 in blue light exposure.ARABIAN JOURNAL OF CHEMISTRY,12(7),957-965.
MLA Kadi, Mohammad W.,et al."The effect of Pt nanoparticles distribution on the removal of cyanide by TiO2 coated Al-MCM-41 in blue light exposure".ARABIAN JOURNAL OF CHEMISTRY 12.7(2019):957-965.

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来源:金属研究所

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