中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
首页 机构 成果 学者
  
  1. CAS IR Grid
  2. 金属研究所
  3. 中国科学院金属研究所
Ultrafast growth of nanocrystalline graphene films by quenching and grain-size-dependent strength and bandgap opening

文献类型：期刊论文

作者Zhao, Tong1,2; Xu, Chuan1; Ma, Wei1,2; Liu, Zhibo1; Zhou, Tianya1,2; Liu, Zhen3,6; Feng, Shun1; Zhu, Mengjian5; Kang, Ning3,6; Sun, Dong-Ming1
刊名NATURE COMMUNICATIONS
出版日期2019-10-24
卷号10页码:10
ISSN号2041-1723
DOI10.1038/s41467-019-12662-z
通讯作者Ren, Wencai(wcren@imr.ac.cn)
英文摘要Nanocrystallization is a well-known strategy to dramatically tune the properties of materials; however, the grain-size effect of graphene at the nanometer scale remains unknown experimentally because of the lack of nanocrystalline samples. Here we report an ultrafast growth of graphene films within a few seconds by quenching a hot metal foil in liquid carbon source. Using Pt foil and ethanol as examples, four kinds of nanocrystalline graphene films with average grain size of similar to 3.6, 5.8, 8.0, and 10.3 nm are synthesized. It is found that the effect of grain boundary becomes more pronounced at the nanometer scale. In comparison with pristine graphene, the 3.6 nm-grained film retains high strength (101 GPa) and Young's modulus (576 GPa), whereas the electrical conductivity is declined by over 100 times, showing semiconducting behavior with a bandgap of similar to 50 meV. This liquid-phase precursor quenching method opens possibilities for ultrafast synthesis of typical graphene materials and other two-dimensional nanocrystalline materials.
资助项目National Key R&D Program of China[2016YFA0200101] ; National Science Foundation of China[51325205] ; National Science Foundation of China[51290273] ; National Science Foundation of China[51521091] ; Strategic Priority Research Program of Chinese Academy of Sciences[XDB30000000] ; Chinese Academy of Sciences[ZDBS LY JSC027] ; LiaoNing Revitalization Talents Program[XLYC1808013] ; SYNL-T.S. K Research Fellowship ; Youth Innovation Promotion Association of the Chinese Academy of Sciences ; Program for Guangdong Introducing Innovative and Enterpreneurial Teams[2017ZT07C341] ; Bureau of Industry and Information Technology of Shenzhen[201901171523] ; Development and Reform Commission of Shenzhen Municipality for the development of the Low-Dimensional Materials and Devices discipline
WOS研究方向Science & Technology - Other Topics
语种英语
WOS记录号WOS:000492140800010
出版者NATURE PUBLISHING GROUP
资助机构National Key R&D Program of China ; National Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Chinese Academy of Sciences ; LiaoNing Revitalization Talents Program ; SYNL-T.S. K Research Fellowship ; Youth Innovation Promotion Association of the Chinese Academy of Sciences ; Program for Guangdong Introducing Innovative and Enterpreneurial Teams ; Bureau of Industry and Information Technology of Shenzhen ; Development and Reform Commission of Shenzhen Municipality for the development of the Low-Dimensional Materials and Devices discipline
源URL[http://ir.imr.ac.cn/handle/321006/137054]  
专题金属研究所_中国科学院金属研究所
通讯作者Ren, Wencai
作者单位1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China
2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Liaoning, Peoples R China
3.Peking Univ, Key Lab Phys & Chem Nanodevices, Beijing 100871, Peoples R China
4.Tsinghua Univ, TBSI, Shenzhen Geim Graphene Ctr, Shenzhen 518055, Peoples R China
5.Natl Univ Def Technol, Coll Adv Interdisciplinary Studies, Changsha 410073, Hunan, Peoples R China
6.Peking Univ, Dept Elect, Beijing 100871, Peoples R China
推荐引用方式
GB/T 7714		 Zhao, Tong,Xu, Chuan,Ma, Wei,et al. Ultrafast growth of nanocrystalline graphene films by quenching and grain-size-dependent strength and bandgap opening[J]. NATURE COMMUNICATIONS,2019,10:10.
APA Zhao, Tong.,Xu, Chuan.,Ma, Wei.,Liu, Zhibo.,Zhou, Tianya.,...&Ren, Wencai.(2019).Ultrafast growth of nanocrystalline graphene films by quenching and grain-size-dependent strength and bandgap opening.NATURE COMMUNICATIONS,10,10.
MLA Zhao, Tong,et al."Ultrafast growth of nanocrystalline graphene films by quenching and grain-size-dependent strength and bandgap opening".NATURE COMMUNICATIONS 10(2019):10.

入库方式： OAI收割

来源：金属研究所

浏览0
下载0
收藏0
其他版本

除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。