Cu-based metallic glass with robust activity and sustainability for wastewater treatment
文献类型：期刊论文
| 作者 | Li, Zhengkun1; Qin, Xindong2; Zhu, Zhengwang1; Zheng, Shijian3; Li, Hailong1; Fu, Huameng1; Zhang, Haifeng1 |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY A
 |
| 出版日期 | 2020-06-07 |
| 卷号 | 8期号:21页码:10855-10864 |
| ISSN号 | 2050-7488 |
| DOI | 10.1039/d0ta01693d |
| 通讯作者 | Zhu, Zhengwang(zwzhu@imr.ac.cn) ; Zhang, Haifeng(hfzhang@imr.ac.cn) |
| 英文摘要 | Metallic glasses (MGs) with superior catalytic performance have attracted great attention in wastewater treatment. However, the low durability of the extensively studied Fe-based MGs impedes their degradation efficiencies and practical applications. In this study, Cu46Zr44.5Al7.5Gd2 MGs are prepared to degrade organic water contaminants for the first time, and they exhibit excellent catalytic activity and high sustainability. The degradation reactions maintain a high degradation efficiency of more than 95% within 10 min when the Cu-based MG ribbons are reused 80 times. The degradation reaction occurs more easily with the Cu-based MGs compared with other MGs due to the lower thermal activation energy barrier of 17 kJ mol(-1). Cu nanocrystals precipitating in the Cu-based MGs are the catalytically active species of the degradation reaction, resulting in the high degradation efficiency and sustainability of the Cu-based MGs. Our study will promote the widespread application of MGs as functional materials. |
| 资助项目 | National Natural Science Foundation of China[51801209] ; Natural Science Foundation of Liaoning Province of China[20180550338] ; Natural Science Foundation of Liaoning Province of China[2019-ZD-0195] ; fund of the Shenyang National Laboratory for Materials Science[L2019F41] ; Natural Science Foundation of Liaoning University[LDQN2019020] ; Liaoning Revitalization Talents Program[XLYC1802078] ; Liaoning Revitalization Talents Program[XLYC1807062] |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000538143000021 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | National Natural Science Foundation of China ; Natural Science Foundation of Liaoning Province of China ; fund of the Shenyang National Laboratory for Materials Science ; Natural Science Foundation of Liaoning University ; Liaoning Revitalization Talents Program |
| 源URL | [http://ir.imr.ac.cn/handle/321006/139072]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Zhu, Zhengwang; Zhang, Haifeng |
| 作者单位 | 1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 2.Liaoning Univ, Coll Chem, Inst Rare & Scattered Elements, Shenyang 110036, Peoples R China 3.Hebei Univ Technol, State Key Lab Reliabil & Intelligence Elect Equip, Tianjin 300401, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Zhengkun,Qin, Xindong,Zhu, Zhengwang,et al. Cu-based metallic glass with robust activity and sustainability for wastewater treatment[J]. JOURNAL OF MATERIALS CHEMISTRY A,2020,8(21):10855-10864. |
| APA | Li, Zhengkun.,Qin, Xindong.,Zhu, Zhengwang.,Zheng, Shijian.,Li, Hailong.,...&Zhang, Haifeng.(2020).Cu-based metallic glass with robust activity and sustainability for wastewater treatment.JOURNAL OF MATERIALS CHEMISTRY A,8(21),10855-10864. |
| MLA | Li, Zhengkun,et al."Cu-based metallic glass with robust activity and sustainability for wastewater treatment".JOURNAL OF MATERIALS CHEMISTRY A 8.21(2020):10855-10864. |
入库方式： OAI收割
来源：金属研究所
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