中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Deposition of highly adhesive nanocrystalline diamond films on Ti substrates via diamond/SiC composite interlayers

文献类型:期刊论文

作者Yang, Bing2; Li, Haining1,2; Yu, Biao1,2; Huang, Nan2; Liu, Lusheng2; Jiang, Xin2
刊名DIAMOND AND RELATED MATERIALS
出版日期2020-10-01
卷号108页码:10
关键词Diamond film Chemical vapor deposition Microstructure Film adhesion High resolution transmission electron microscopy
ISSN号0925-9635
DOI10.1016/j.diamond.2020.107928
通讯作者Yang, Bing(byang@imr.ac.cn) ; Jiang, Xin(xjiang@imr.ac.cn)
英文摘要Diamond/SiC interlayer with intermediate thermal expansion coefficient is introduced for improving the adhesion of NCD films on Ti substrate. Herein, tetramethylsilane (TMS) gas is added to produce SiC phase, forming a diamond/SiC interlayer. The effect of TMS gas flow on the microstructural evolution of the interfacial layer and the film adhesion is systematically investigated. At TMS gas flow of 5 sccm, the NCD film shows an interlayer of about 15% SiC by phase area statistics in SEM image. This film exhibits the lowest residual compressive stress of 1.64 GPa and the optimum adhesion of about 28.2 +/- 2 N against Ti substrate. Increasing TMS gas flow leads to the increase of SiC content and the grain refinement of diamond in the interlayers. It is found that Ti silicide and hydride with increased amount are formed in the Ti substrate at higher TMS gas flow. The presence of these Ti intermetallic compounds with larger thermal expansion coefficient results in the increased residual stress and poorer adhesion in the NCD films. On the basis of reduction of Ti intermetallic compounds, the addition of TMS gas flow at 5 sccm is crucial for the preparation of good-adhesion NCD films on Ti substrate.
资助项目National Natural Science Foundation of China[51872294] ; Liaoning Provincial Natural Science Foundation of China[Y931L90381] ; Institute of Metal Research, Chinese Academy of Sciences[Y5NCA111A1] ; Institute of Metal Research, Chinese Academy of Sciences[Y6NC6F1161]
WOS研究方向Materials Science ; Physics
语种英语
WOS记录号WOS:000569885400012
出版者ELSEVIER SCIENCE SA
资助机构National Natural Science Foundation of China ; Liaoning Provincial Natural Science Foundation of China ; Institute of Metal Research, Chinese Academy of Sciences
源URL[http://ir.imr.ac.cn/handle/321006/140505]  
专题金属研究所_中国科学院金属研究所
通讯作者Yang, Bing; Jiang, Xin
作者单位1.Univ Sci & Technol China, Dept Mat Sci & Engn, Hefei 230026, Peoples R China
2.Chinese Acad Sci, Inst Met Res IMR, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Peoples R China
推荐引用方式
GB/T 7714
Yang, Bing,Li, Haining,Yu, Biao,et al. Deposition of highly adhesive nanocrystalline diamond films on Ti substrates via diamond/SiC composite interlayers[J]. DIAMOND AND RELATED MATERIALS,2020,108:10.
APA Yang, Bing,Li, Haining,Yu, Biao,Huang, Nan,Liu, Lusheng,&Jiang, Xin.(2020).Deposition of highly adhesive nanocrystalline diamond films on Ti substrates via diamond/SiC composite interlayers.DIAMOND AND RELATED MATERIALS,108,10.
MLA Yang, Bing,et al."Deposition of highly adhesive nanocrystalline diamond films on Ti substrates via diamond/SiC composite interlayers".DIAMOND AND RELATED MATERIALS 108(2020):10.

入库方式: OAI收割

来源:金属研究所

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