Mechanism of Chromium Electrodeposition from Cr(III) Baths on Nickel and Chromium Electrode Surfaces
文献类型：期刊论文
| 作者 | Zhao, Huan1,2; Liu, Weihua1; Li, Qingpeng1; Zhang, Bo1; Liu, Jianguo1; Yan, Chuanwei1; Liu, Chunming2 |
| 刊名 | INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
 |
| 出版日期 | 2020-09-01 |
| 卷号 | 15期号:9页码:8979-8989 |
| 关键词 | Trivalent chromium Hard chromium electrodeposition mechanism Nickel electrode Chromium coating electrode |
| ISSN号 | 1452-3981 |
| DOI | 10.20964/2020.09.23 |
| 通讯作者 | Zhao, Huan(hzhao@imr.ac.cn) |
| 英文摘要 | The electrode state changes with the thickening of the coating in Cr(III) thick chromium plating. The deposition of Cr(III) is carried out on the substrate at the beginning of deposition and on the chromium coating when the chromium coating becomes thicker. The aim of this work is to study the influence of the change of electrode state on the reduction mechanism of trivalent chromium. The electrodeposition mechanism of Cr(III) is studied by cyclic voltammetry, electrochemical impendance spectroscopy, chronoamperometry and polarization technique. The results show that the reduction of Cr(III) on chromium coating electrode has a negative deposition potential, higher charge transfer resistance, higher activation energy, and lower diffusion coefficient than those on the nickel electrode, the reduction of Cr(III) is more difficult on chromium coating electrode. The change of electrode state is one of the reasons for the difficulty in thickening of chromium coating. |
| WOS研究方向 | Electrochemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000570963900048 |
| 出版者 | ESG |
| 源URL | [http://ir.imr.ac.cn/handle/321006/140618]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Zhao, Huan |
| 作者单位 | 1.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China 2.Northeastern Univ, Sch Mat Sci & Engn, Shenyang 110819, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, Huan,Liu, Weihua,Li, Qingpeng,et al. Mechanism of Chromium Electrodeposition from Cr(III) Baths on Nickel and Chromium Electrode Surfaces[J]. INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE,2020,15(9):8979-8989. |
| APA | Zhao, Huan.,Liu, Weihua.,Li, Qingpeng.,Zhang, Bo.,Liu, Jianguo.,...&Liu, Chunming.(2020).Mechanism of Chromium Electrodeposition from Cr(III) Baths on Nickel and Chromium Electrode Surfaces.INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE,15(9),8979-8989. |
| MLA | Zhao, Huan,et al."Mechanism of Chromium Electrodeposition from Cr(III) Baths on Nickel and Chromium Electrode Surfaces".INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE 15.9(2020):8979-8989. |
入库方式： OAI收割
来源：金属研究所
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