CdPS3 nanosheets-based membrane with high proton conductivity enabled by Cd vacancies
文献类型：期刊论文
| 作者 | Qian, Xitang3,4; Chen, Long3; Yin, Lichang3; Liu, Zhibo3; Pei, Songfeng3; Li, Fan2,5; Hou, Guangjin2; Chen, Shuangming6; Song, Li6; Thebo, Khalid Hussain3 |
| 刊名 | SCIENCE
 |
| 出版日期 | 2020-10-30 |
| 卷号 | 370期号:6516页码:596-+ |
| ISSN号 | 0036-8075 |
| DOI | 10.1126/science.abb9704 |
| 通讯作者 | Ren, Wencai(wcren@imr.ac.cn) |
| 英文摘要 | Proton transport in nanochannels under humid conditions is crucial for the application in energy storage and conversion. However, existing materials, including Nafion, suffer from limited conductivity of up to 0.2 siemens per centimeter. We report a class of membranes assembled with two-dimensional transition-metal phosphorus trichalcogenide nanosheets, in which the transition-metal vacancies enable exceptionally high ion conductivity. A Cd0.85PS3Li0.15H0.15 membrane exhibits a proton conduction dominant conductivity of similar to 0.95 siemens per centimeter at 90 degrees Celsius and 98% relative humidity. This performance mainly originates from the abundant proton donor centers, easy proton desorption, and excellent hydration of the membranes induced by cadmium vacancies. We also observed superhigh lithium ion conductivity in Cd0.5PS3Li0.3 and Mn0.77PS3Li0.46 membranes. |
| 资助项目 | National Natural Science Foundation of China[51325205] ; National Natural Science Foundation of China[51290273] ; National Natural Science Foundation of China[51521091] ; National Natural Science Foundation of China[51972312] ; Key Research Program of Frontier Sciences of the Chinese Academy of Sciences[ZDBS-LY-JSC027] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDB30000000] ; National Key R&D Program of the Ministry of Science and Technology of China[2016YFA0200101] ; LiaoNing Revitalization Talents Program[XLYC1808013] ; Program for Guangdong Introducing Innovative and Enterpreneurial Teams ; Development and Reform Commission of Shenzhen Municipality for the development of the Low-Dimensional Materials and Devices discipline |
| WOS研究方向 | Science & Technology - Other Topics |
| 语种 | 英语 |
| 出版者 | AMER ASSOC ADVANCEMENT SCIENCE |
| WOS记录号 | WOS:000583031800050 |
| 资助机构 | National Natural Science Foundation of China ; Key Research Program of Frontier Sciences of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key R&D Program of the Ministry of Science and Technology of China ; LiaoNing Revitalization Talents Program ; Program for Guangdong Introducing Innovative and Enterpreneurial Teams ; Development and Reform Commission of Shenzhen Municipality for the development of the Low-Dimensional Materials and Devices discipline |
| 源URL | [http://ir.imr.ac.cn/handle/321006/141162]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Ren, Wencai |
| 作者单位 | 1.Tsinghua Univ, Tsinghua Berkeley Shenzhen Inst TBSI, 1001 Xueyuan Rd, Shenzhen 518055, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Peoples R China 4.Univ Sci & Technol China, Sch Mat Sci & Engn, 72 Wenhua Rd, Shenyang 110016, Peoples R China 5.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 6.Univ Sci & Technol China, Natl Synchrotron Radiat Lab, Hefei 230029, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qian, Xitang,Chen, Long,Yin, Lichang,et al. CdPS3 nanosheets-based membrane with high proton conductivity enabled by Cd vacancies[J]. SCIENCE,2020,370(6516):596-+. |
| APA | Qian, Xitang.,Chen, Long.,Yin, Lichang.,Liu, Zhibo.,Pei, Songfeng.,...&Ren, Wencai.(2020).CdPS3 nanosheets-based membrane with high proton conductivity enabled by Cd vacancies.SCIENCE,370(6516),596-+. |
| MLA | Qian, Xitang,et al."CdPS3 nanosheets-based membrane with high proton conductivity enabled by Cd vacancies".SCIENCE 370.6516(2020):596-+. |
入库方式： OAI收割
来源：金属研究所
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