Synthesis and crystal structure of a 2D coordination polymer: Nd-2(PDB)(2)(CH3COO)(2)(H2O)(3)
文献类型：期刊论文
| 作者 | Gu XiaoFu; Sun YaGuang; Gao EnJun; Yan XiaoMei |
| 刊名 | CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
 |
| 出版日期 | 2008 |
| 卷号 | 27期号:1页码:112-116 |
| 关键词 | Nd(III) crystal structure coordination polymer |
| ISSN号 | 0254-5861 |
| 其他题名 | Synthesis and Crystal Structure of a 2D Coordination Polymer： Nd_2（PDB）_2（CH_3COO）_2（H_2O）_3 |
| 英文摘要 | A novel coordination polymer Nd-2(PDB3)(2)(CH3COO)(2)(H2O)(3) (H2PDB = pyridine-3,4-dicarboxylic acid) has been synthesized by the reaction of Nd(CH3COO)(3) With pyridine-3,4-dicarboxylic acid under hydrothermal conditions. Elemental analysis, IR spectra and X-ray crystal structure analysis were carried out to determine the composition and crystal structure of the title complex which belongs to the triclinic system, space group Pi with a = 6.9409(14), b = 7.5497(15), c = 22.530(5) angstrom, a = 84.79(3), beta = 88.15(3), gamma = 75.55(3)degrees, C18H18N2O15Nd2, M-r = 790.82, Z = 2, V = 1138.5(4) angstrom(3), D-c = 2.307 g/cm(3), mu = 4.593 mm(-1), -6, 2 sigma(I)). Nd(1) and Nd(2) are linked into zigzag chains by carboxylate groups of acetate with interesting mu(3)-eta(2):eta(2) fashion. The zigzag. chains are bridged by PDB to form a 2D framework, and a 3D supramolecular network is further constructed via pi-pi stacking. |
| 语种 | 英语 |
| CSCD记录号 | CSCD:3249801 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/142711]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 作者单位 | 中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | Gu XiaoFu,Sun YaGuang,Gao EnJun,et al. Synthesis and crystal structure of a 2D coordination polymer: Nd-2(PDB)(2)(CH3COO)(2)(H2O)(3)[J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,2008,27(1):112-116. |
| APA | Gu XiaoFu,Sun YaGuang,Gao EnJun,&Yan XiaoMei.(2008).Synthesis and crystal structure of a 2D coordination polymer: Nd-2(PDB)(2)(CH3COO)(2)(H2O)(3).CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,27(1),112-116. |
| MLA | Gu XiaoFu,et al."Synthesis and crystal structure of a 2D coordination polymer: Nd-2(PDB)(2)(CH3COO)(2)(H2O)(3)".CHINESE JOURNAL OF STRUCTURAL CHEMISTRY 27.1(2008):112-116. |
入库方式： OAI收割
来源：金属研究所
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