Influence of Concentration Sequence on the Signal-to-Noise Ratio of Cross Peaks of 2D Asynchronous Spectra Generated by Using the DAOSD Approach
文献类型：期刊论文
| 作者 | Zhang Jin2; Guo Ran3; Kang Tingguo2; He Anqi3; Weng Shifu3; Xia Jinming1; Ling Xiaofeng3; Xu Yizhuang3; Wu Jinguang3 |
| 刊名 | SPECTROSCOPY AND SPECTRAL ANALYSIS
 |
| 出版日期 | 2015 |
| 卷号 | 35期号:5页码:1193-1198 |
| 关键词 | SAMPLE DESIGN SCHEME 2-DIMENSIONAL SYNCHRONOUS SPECTROSCOPY PROBING INTERMOLECULAR INTERACTIONS DIPOLE-DIPOLE INTERACTIONS SOLUTION MIXTURES AOSD APPROACH COORDINATION RAMAN ACID DAOSD Infrared spectra Cross peaks intensity |
| ISSN号 | 1000-0593 |
| 其他题名 | Influence of Concentration Sequence on the Signal-to-Noise Ratio of Cross Peaks of 2D Asynchronous Spectra Generated by Using the DAOSD Approach |
| 英文摘要 | In the present work, computer simulation was performed on a model chemical system where two solutes (denoted as P and Q, respectively) are dissolved in the same solution. Under intermolecular interaction between P and Q, part of P undergoes subtle structural variation and converts into U while part of Q converts into V. The strength of intermolecular interaction can be characterized by the corresponding equilibrium constant K. Our preliminary studies indicate that the S/N ratio of cross peak increases considerably as n increases. Moreover, the S/N ratio of the cross peak from the asynchronous spectra can be improved significantly when the suitable concentrations of P and Q are adopted. This work is helpful for a selection of suitable concentration sequence to maximize S/N ratio of cross peaks in the 2D asynchronous spectra generated by using the DAOSD approach proposed in our previous study so that weak intermolecular interaction can be probed. |
| 语种 | 英语 |
| CSCD记录号 | CSCD:5410946 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/143737]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 作者单位 | 1.中国科学院金属研究所 2.辽宁大学 3.北京大学 |
| 推荐引用方式 GB/T 7714 | Zhang Jin,Guo Ran,Kang Tingguo,et al. Influence of Concentration Sequence on the Signal-to-Noise Ratio of Cross Peaks of 2D Asynchronous Spectra Generated by Using the DAOSD Approach[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS,2015,35(5):1193-1198. |
| APA | Zhang Jin.,Guo Ran.,Kang Tingguo.,He Anqi.,Weng Shifu.,...&Wu Jinguang.(2015).Influence of Concentration Sequence on the Signal-to-Noise Ratio of Cross Peaks of 2D Asynchronous Spectra Generated by Using the DAOSD Approach.SPECTROSCOPY AND SPECTRAL ANALYSIS,35(5),1193-1198. |
| MLA | Zhang Jin,et al."Influence of Concentration Sequence on the Signal-to-Noise Ratio of Cross Peaks of 2D Asynchronous Spectra Generated by Using the DAOSD Approach".SPECTROSCOPY AND SPECTRAL ANALYSIS 35.5(2015):1193-1198. |
入库方式： OAI收割
来源：金属研究所
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