Synthesis and crystal structure of a novel tetranuclear complex P(b)4(HQ)(6)(NO3)(2)
文献类型：期刊论文
| 作者 | Zhang WanZhong1; Wei DeZhou2; Che XiaoFei1; Gao EnJun1; Wang KeHua1; Yin HongXi1; Gu XiaoFu1 |
| 刊名 | CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
 |
| 出版日期 | 2008 |
| 卷号 | 27期号:3页码:287-292 |
| 关键词 | NITROGEN-DONOR MACROCYCLE COORDINATION GEOMETRY LONE-PAIR LEAD(II) STEREOCHEMISTRY BISMUTH(III) ISOMERS LIGANDS HALIDES RADII Pb(II) complex X-ray structure luminescent property |
| ISSN号 | 0254-5861 |
| 其他题名 | Synthesis and Crystal Structure of a Novel Tetranuclear Complex Pb_4（HQ）_6（NO_3）_2 |
| 英文摘要 | Reaction of 8-hydroxyquinoline (HQ) with Pb(NO3)(2) in water resulted in the formation of a tetranuclear complex Pb-4(HQ)(6)(NO3)(2) 1. It has been characterized by IR, elemental analyses and X-ray diffraction. Crystal data for this complex: triclinic system, space group P (1) over bar, a = 9.7399(6), b = 11.6535(8), c = 12.6806(8) angstrom, alpha = 62.8050(10), beta = 78.4010(10), gamma = 80.54 0(10)degrees, C54H36N8O12Pb4, M-r = 1817.67, Z = 1, V = 1250.04(14) angstrom(3), D-c = 2.415 g/cm(3), mu = 13.503 mm(-1), -12 <= h <= 8,-14 <= k <= 13,-15 <= l <= 15, F(000) = 840, R-int = 0.0217, R= 0.0348 and wR = 0.0927. X-ray crystal structure analysis revealed that in 1 each Pb(H) contains a stereochemically active lone pair of electrons. The Pb center dot center dot center dot C interaction, C-H center dot center dot center dot O weak interaction and pi center dot center dot center dot pi stacking interactions are observed in the complex. In the solid state, the complex possesses strong photoluminescent emission at 485 and 528 nm. |
| 语种 | 英语 |
| CSCD记录号 | CSCD:3249843 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/147761]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 作者单位 | 1.中国科学院金属研究所 2.东北大学 |
| 推荐引用方式 GB/T 7714 | Zhang WanZhong,Wei DeZhou,Che XiaoFei,et al. Synthesis and crystal structure of a novel tetranuclear complex P(b)4(HQ)(6)(NO3)(2)[J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,2008,27(3):287-292. |
| APA | Zhang WanZhong.,Wei DeZhou.,Che XiaoFei.,Gao EnJun.,Wang KeHua.,...&Gu XiaoFu.(2008).Synthesis and crystal structure of a novel tetranuclear complex P(b)4(HQ)(6)(NO3)(2).CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,27(3),287-292. |
| MLA | Zhang WanZhong,et al."Synthesis and crystal structure of a novel tetranuclear complex P(b)4(HQ)(6)(NO3)(2)".CHINESE JOURNAL OF STRUCTURAL CHEMISTRY 27.3(2008):287-292. |
入库方式： OAI收割
来源：金属研究所
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