On the Tributylphosphate-Based Super-Concentrated HCl System
文献类型：期刊论文
| 作者 | Guo Lin1; Huang Kun3; Guo Ran2; He Anqi2; Weng Shifu2; Yang Zhanlan2; Zhao Ying3; Xia Jinming4; Xu Yizhuang2; Kang Tingguo1 |
| 刊名 | SPECTROSCOPY AND SPECTRAL ANALYSIS
 |
| 出版日期 | 2015 |
| 卷号 | 35期号:8页码:2241-2245 |
| 关键词 | ACID Tributyl phosphate (TBP) Super-concentrated HCl n(H)+/nH(2)O Copper ion |
| ISSN号 | 1000-0593 |
| 其他题名 | On the Tributylphosphate-Based Super-Concentrated HCl System |
| 英文摘要 | We reported a new super-concentrated hydrochloric acid system prepared by using tri-n-butyl phosphate (TBP)-constructed reversed micelles at ambient temperature and pressure. According to the titration result, the molar ratio of H+ to H2O (denoted as n(H)+/nH(2)O) in the super-concentrated HCl range from 0. 50 to 1. 50 which are higher than that in saturated aqueous HCl bulk solution (0. 28). Significant a moment of hydrochloric acid is confined in W/O reversed micelles. Therefore, the behavior and status of HCl are different from those of conventional bluk solution. FTIR spectroscopic results demonstrate that a significant amount of HCl remains in the molecular form rather than being ionized into H+ and Cl-. Thus, super-concentrated HCl provides an extraordinary chemical environment which may have significant influence on certain substances. We found that the color of the solution is reddish brown when copper ion is dissolved in super-concentrated HCl, while the color of the saturated HCl aqueous solution (37 Wt%) containing copper ion is green. That is to say, the copper ions exist in a special state under the unique chemical environment of super-concentrated HCl. UV-Vis-NIR spectra indicate that both d-d transition band and charge transfer transition band of copper ions in super-concentrated HCl solution underwent significant variations. In addition, copper ions also have obvious influence on the hydrogen bond network among HCl in the super-concentrated HCl solution. Remarkable variation is introduced in the H-Cl stretching band in FTIR spectra. |
| 语种 | 英语 |
| CSCD记录号 | CSCD:5481746 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/147838]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 作者单位 | 1.辽宁大学 2.北京大学 3.中国科学院 4.中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | Guo Lin,Huang Kun,Guo Ran,et al. On the Tributylphosphate-Based Super-Concentrated HCl System[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS,2015,35(8):2241-2245. |
| APA | Guo Lin.,Huang Kun.,Guo Ran.,He Anqi.,Weng Shifu.,...&Wu Jinguang.(2015).On the Tributylphosphate-Based Super-Concentrated HCl System.SPECTROSCOPY AND SPECTRAL ANALYSIS,35(8),2241-2245. |
| MLA | Guo Lin,et al."On the Tributylphosphate-Based Super-Concentrated HCl System".SPECTROSCOPY AND SPECTRAL ANALYSIS 35.8(2015):2241-2245. |
入库方式： OAI收割
来源：金属研究所
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