Synthesis and Structure of a Novel Macrocyclic Complex Cd2(phen)4(phth)2·4H2O
文献类型:期刊论文
作者 | SUNYaGuang; GAOEnJun; WEIDeZhou; LIUYiNan |
刊名 | 结构化学
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出版日期 | 2005 |
卷号 | 24.0期号:011页码:1298-1301 |
关键词 | 镉 晶体结构 氢焊接法 合成方法 水成反应 |
ISSN号 | 0254-5861 |
其他题名 | Synthesis and Structure of a Novel Macrocyclic Complex Cd2(phen)4(phth)2·4H2O |
英文摘要 | A novel complex Cd2(phen)4(phth)2·4H2O has been synthesized by the reaction of Hzphth(phthalic acid) and phen(1,10-phenanthroline) with Cd(Ⅱ) in ethanol-water solution. X-ray crystal structure analysis shows it crystallizes in triclinic, space group PI- with a = 10.619(3), b = 12.560(4), c = 12.651(4) A, a = 98.775(5), β = 109.035(5),γ = 113-576(5)°, C32H24CdN4O6, Mr= 672.95, V = 1381.7(7)A^3, Rint = 0.0358, Z = 2, Dc= 1.618 g/cm^3,μ = 0.845 mm^-1, -6 ≤h≤13, -15 ≤k ≤13, -15 ≤l≤14, F(000) = 680, S = 1.038, R = 0.0480 and wR = 0.0849 for 3992 observed reflections (1 〉 2σ(Ⅰ)). Phth bridges Cd(Ⅱ) to form a macrocyclic compound, and a 2D supramolecular motif is formed through hydrogen bonds and π-π interaction. |
语种 | 中文 |
CSCD记录号 | CSCD:2164814 |
源URL | [http://ir.imr.ac.cn/handle/321006/149653] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
作者单位 | 中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | SUNYaGuang,GAOEnJun,WEIDeZhou,等. Synthesis and Structure of a Novel Macrocyclic Complex Cd2(phen)4(phth)2·4H2O[J]. 结构化学,2005,24.0(011):1298-1301. |
APA | SUNYaGuang,GAOEnJun,WEIDeZhou,&LIUYiNan.(2005).Synthesis and Structure of a Novel Macrocyclic Complex Cd2(phen)4(phth)2·4H2O.结构化学,24.0(011),1298-1301. |
MLA | SUNYaGuang,et al."Synthesis and Structure of a Novel Macrocyclic Complex Cd2(phen)4(phth)2·4H2O".结构化学 24.0.011(2005):1298-1301. |
入库方式: OAI收割
来源:金属研究所
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