Electrochemical Deposition and Nucleation of Aluminum on Tungsten in Aluminum Chloride-Sodium Chloride Melts
文献类型：期刊论文
| 作者 | Wang Zhaowen; Kan Hongmin; Shi Zhongning; Gao Bingliang; Ban Yungang; Hu Xianwei |
| 刊名 | JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
 |
| 出版日期 | 2008 |
| 卷号 | 24期号:6页码:915-920 |
| 关键词 | TEMPERATURE CHLOROALUMINATE MELTS AMORPHOUS-CARBON ELECTRODES MOLTEN-SALT IONIC LIQUIDS ELECTROCRYSTALLIZATION ALCL3-NACL-KCL MORPHOLOGY GROWTH COPPER SILVER Electrochemical deposition Aluminum-sodium chloride melts Aluminum Tungsten Nucleation |
| ISSN号 | 1005-0302 |
| 其他题名 | Electrochemical Deposition and Nucleation of Aluminum on Tungsten in Aluminum Chloride-Sodium Chloride Melts |
| 英文摘要 | Electrochemical deposition and nucleation of aluminum on tungsten electrode from AlCl(3)-NaCl melts were studied by cyclic voltammetry, chronopotentiometry and chronoamperometry. Cyclic voltammetry and chronopotentiometry analyses showed that Al (III) was reduced at 200 degrees C in two consecutive steps in an electrolyte of molten AlCl(3)-NaCl system with a composition 52:48 molar ratio. The current-time characteristics of nucleation aluminum on tungsten showed a strong dependence on overpotentials. Chronoamperometry showed that the deposition process of aluminum on tungsten was controlled by an instantaneous nucleation with a hemispherical diffusion-controlled growth mechanism. The results could lead to a better understanding of the AlCl(3)-NaCl melt system that has technological importance in electrodeposition of metals as well as in rechargeable batteries. |
| 资助项目 | [National Basic Research Program of China] ; [National Natural Science Foundation of China] |
| 语种 | 英语 |
| CSCD记录号 | CSCD:3580263 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/152083]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 作者单位 | 中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | Wang Zhaowen,Kan Hongmin,Shi Zhongning,et al. Electrochemical Deposition and Nucleation of Aluminum on Tungsten in Aluminum Chloride-Sodium Chloride Melts[J]. JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,2008,24(6):915-920. |
| APA | Wang Zhaowen,Kan Hongmin,Shi Zhongning,Gao Bingliang,Ban Yungang,&Hu Xianwei.(2008).Electrochemical Deposition and Nucleation of Aluminum on Tungsten in Aluminum Chloride-Sodium Chloride Melts.JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,24(6),915-920. |
| MLA | Wang Zhaowen,et al."Electrochemical Deposition and Nucleation of Aluminum on Tungsten in Aluminum Chloride-Sodium Chloride Melts".JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY 24.6(2008):915-920. |
入库方式： OAI收割
来源：金属研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。