Core@shell sub-ten-nanometer noble metal nanoparticles with a controllable thin Pt shell and their catalytic activity towards oxygen reduction
文献类型:期刊论文
作者 | Deogratias Ntirikwendera2; Ji Muwei2; Zhang Yong2; Liu Jiajia2; Zhang Jiatao1; Zhu Hesun2 |
刊名 | NANO RESEARCH
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出版日期 | 2015 |
卷号 | 8期号:1页码:271-280 |
关键词 | GALVANIC REPLACEMENT ELECTROCATALYTIC ACTIVITY PLATINUM NANOPARTICLES SILVER NANOPARTICLES ALLOY NANOPARTICLES PT NANOPARTICLES FUEL-CELLS HOLLOW AG NANOSTRUCTURES core@shell metal nanocomposites Pt shell sub-ten-nanometer oxygen reduction |
ISSN号 | 1998-0124 |
其他题名 | Core@shell sub-ten-nanometer noble metal nanoparticles with a controllable thin Pt shell and their catalytic activity towards oxygen reduction |
英文摘要 | Reducing Pt loading, while improving electrocatalytic activity and the stability of Pt-based nanostructured materials, is currently a key challenge in green energy technology. Herein, we report the controllable synthesis of tri-metallic (Au@Ag@Pt) and bimetallic (Ag@Pt) particles consisting of a controllable thin Pt shell, via interface-mediated galvanic displacement. Through oil-ethanol-H2O interface mediation, the controllable "out to in" displacement of Ag atoms to Pt enables the formation of a thin Pt shell on monodisperse sub-ten-nanometer Au@Ag and Ag nanocrystals. The synthesized nanoparticles with a thin Pt shell exhibited potential catalytic activity towards the oxygen reduction reaction (ORR) due to the high exposure of Pt atoms. |
资助项目 | [National Natural Science Foundation] ; [Research Fund for the Doctoral Program of Higher Education of China] ; [Beijing Excellent Talent Training Project] ; [Program for New Century Excellent Talents in University] |
语种 | 英语 |
CSCD记录号 | CSCD:5454007 |
源URL | [http://ir.imr.ac.cn/handle/321006/153306] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
作者单位 | 1.Beijing Institute Technol, Dept Mat Phys & Chem, Beijing 100081, Peoples R China 2.中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | Deogratias Ntirikwendera,Ji Muwei,Zhang Yong,et al. Core@shell sub-ten-nanometer noble metal nanoparticles with a controllable thin Pt shell and their catalytic activity towards oxygen reduction[J]. NANO RESEARCH,2015,8(1):271-280. |
APA | Deogratias Ntirikwendera,Ji Muwei,Zhang Yong,Liu Jiajia,Zhang Jiatao,&Zhu Hesun.(2015).Core@shell sub-ten-nanometer noble metal nanoparticles with a controllable thin Pt shell and their catalytic activity towards oxygen reduction.NANO RESEARCH,8(1),271-280. |
MLA | Deogratias Ntirikwendera,et al."Core@shell sub-ten-nanometer noble metal nanoparticles with a controllable thin Pt shell and their catalytic activity towards oxygen reduction".NANO RESEARCH 8.1(2015):271-280. |
入库方式: OAI收割
来源:金属研究所
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