Catalytic synthesis methods for triazolopyrimidine derivatives
文献类型：期刊论文
| 作者 | Cheng ChunSheng; Gai YongMing; Wang XinLei; Peng Jun |
| 刊名 | CHINESE JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2008 |
| 卷号 | 26期号:7页码:1291-1294 |
| 关键词 | PARAQUAT triazolopyrimidine derivative catalyst Lewis acid green chemistry |
| ISSN号 | 1001-604X |
| 其他题名 | Catalytic Synthesis Methods for Triazolopyrimidine Derivatives |
| 英文摘要 | A new method for catalyzed synthesis of triazolopyrimidine derivatives is reported. Alkylamine reaction with dialkyl cyanodithioiminocarbonate was catalyzed by quaternary ammonium salts at room temperature to yield 3-alkylamine-5-amino-1,2,4-triazole in good quality and high yields. After imidization and reaction with an alpha,beta-unsaturated acid derivative, the reaction intermediate was hydrolyzed in the presence of a Lewis acid to obtain the target product. This novel catalytic method for triazolopyrimidine derivatives can be carried out under inexpensive and mild conditions, and is safe and environmentally friendly. (1)H NMR results for all intermediates are reported. |
| 语种 | 英语 |
| CSCD记录号 | CSCD:3434908 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/153772]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 作者单位 | 中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | Cheng ChunSheng,Gai YongMing,Wang XinLei,et al. Catalytic synthesis methods for triazolopyrimidine derivatives[J]. CHINESE JOURNAL OF CHEMISTRY,2008,26(7):1291-1294. |
| APA | Cheng ChunSheng,Gai YongMing,Wang XinLei,&Peng Jun.(2008).Catalytic synthesis methods for triazolopyrimidine derivatives.CHINESE JOURNAL OF CHEMISTRY,26(7),1291-1294. |
| MLA | Cheng ChunSheng,et al."Catalytic synthesis methods for triazolopyrimidine derivatives".CHINESE JOURNAL OF CHEMISTRY 26.7(2008):1291-1294. |
入库方式： OAI收割
来源：金属研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。