Synthesis of 3-benzyloxy-6-methyl-7-methoxyphenanthrene-9-carboxaldehyde with utilize intramolecular Heck reaction as the key step
文献类型：期刊论文
| 作者 | Song Yanling2; Zhai Xin2; Sun Zhifeng2; Kim Sanghee1; Gong Ping2 |
| 刊名 | CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
 |
| 出版日期 | 2008 |
| 卷号 | 24期号:4页码:445-448 |
| 关键词 | TETRAALKYLAMMONIUM SALTS ANTOFINE phenanthrene-9-carboxyaldehyde synthesis Heck reaction |
| ISSN号 | 1005-9040 |
| 其他题名 | Synthesis of 3-Benzyloxy-6-methyl-7-methoxyphenanthrene-9-carboxaldehyde with Utilize Intramolecular Heck Reaction as the Key Step |
| 英文摘要 | The substituted phenanthrene-9-carboxyaldehydes are very important intermediates for the syntheses of phenanthroindolizidine and phenanthroquinolizidine alkaloids. The novel title compound was prepared from the reaction of 5 steps starting from the condensation of 3-methoxyl-4-methyl-phenylacetic acid and 4-(benzyloxy)-2-iodo-benzaldehyde, followed by esterification, cyclization, reduction, and oxidation. A new method for the preparation of phenanthrene ring via palladium-catalyzed intramolecular Heck reaction was described. The title compound was characterized by IR, (1)H NMR, (13)C NMR, elemental analysis, and MS. |
| 语种 | 英语 |
| CSCD记录号 | CSCD:3370636 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/155270]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 作者单位 | 1.Seoul Natl University, Coll Pharm, Seoul 151742, South Korea 2.中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | Song Yanling,Zhai Xin,Sun Zhifeng,et al. Synthesis of 3-benzyloxy-6-methyl-7-methoxyphenanthrene-9-carboxaldehyde with utilize intramolecular Heck reaction as the key step[J]. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,2008,24(4):445-448. |
| APA | Song Yanling,Zhai Xin,Sun Zhifeng,Kim Sanghee,&Gong Ping.(2008).Synthesis of 3-benzyloxy-6-methyl-7-methoxyphenanthrene-9-carboxaldehyde with utilize intramolecular Heck reaction as the key step.CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,24(4),445-448. |
| MLA | Song Yanling,et al."Synthesis of 3-benzyloxy-6-methyl-7-methoxyphenanthrene-9-carboxaldehyde with utilize intramolecular Heck reaction as the key step".CHEMICAL RESEARCH IN CHINESE UNIVERSITIES 24.4(2008):445-448. |
入库方式： OAI收割
来源：金属研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。