Structured silicalite-1 encapsulated Ni catalyst supported on SiC foam for dry reforming of methane
文献类型：期刊论文
| 作者 | Chen, Huanhao2; Shao, Yan1; Mu, Yibing3; Xiang, Huan3; Zhang, Rongxin3; Chang, Yabin5; Hardacre, Christopher3; Wattanakit, Chularat6,7; Jiao, Yilai4; Fan, Xiaolei3 |
| 刊名 | AICHE JOURNAL
 |
| 出版日期 | 2020-12-31 |
| 页码 | 15 |
| 关键词 | anti-sintering and -coking dry reforming of methane (DRM) encapsulated Ni catalyst silicalite-1 silicon carbide (SiC) foam |
| ISSN号 | 0001-1541 |
| DOI | 10.1002/aic.17126 |
| 通讯作者 | Chen, Huanhao(h.chen@njtech.edu.cn) ; Jiao, Yilai(yljiao@imr.ac.cn) ; Fan, Xiaolei(xiaolei.fan@manchester.ac.uk) |
| 英文摘要 | Structured silicalite-1 zeolite encapsulated Ni catalyst supported on silicon carbide foam (i.e., Ni@S1-SiC) was prepared using a new yet simple one-pot method, showing the significantly improved anti-sintering and anti-coking performance in comparison with the conventional supported and encapsulated Ni catalysts (i.e., Ni/S1, Ni/S1-SiC, and Ni@S1), in catalytic dry reforming of methane (DRM). The developed Ni-0.08@S1-SiC catalyst showed high CO2/CH4 conversions of >85% and H-2/CO molar ratio of >0.85 at 700 degrees C, outperforming other control catalysts under investigation. Additionally, the Ni-0.08@S1-SiC catalyst demonstrated high turnover frequency (TOF) values of similar to 5.6 and similar to 2.1/s regarding to CO2/CH4 conversions at 400 degrees C, exhibiting excellent stability and low pressure-drop during 100 hr on stream evaluation. Post-reaction characterization of the used catalysts demonstrated that the combination of zeolite encapsulated Ni catalysts and SiC foam enabled well-dispersed and ultrafine Ni nanoparticles, low pressure drop and intensified transfer steps, presented excellent anti-sintering and anti-coking abilities. |
| 资助项目 | European Commission Horizon 2020 Marie Sklodowska-Curie, Research and Innovation Staff Exchange (RISE) project[H2020-MSCA-RISE-ZEOBIOCHEM-872102] ; Jiangsu Specially-Appointed Professors Program ; Natural Science Foundation of Jiangsu Province[BK20200704] ; China Scholarship Council[201606150068] ; University of Manchester President's Doctoral Scholar Award |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000603681600001 |
| 出版者 | WILEY |
| 资助机构 | European Commission Horizon 2020 Marie Sklodowska-Curie, Research and Innovation Staff Exchange (RISE) project ; Jiangsu Specially-Appointed Professors Program ; Natural Science Foundation of Jiangsu Province ; China Scholarship Council ; University of Manchester President's Doctoral Scholar Award |
| 源URL | [http://ir.imr.ac.cn/handle/321006/158874]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Chen, Huanhao; Jiao, Yilai; Fan, Xiaolei |
| 作者单位 | 1.Nanjing Tech Univ, Sch Environm Sci & Engn, Nanjing, Peoples R China 2.Nanjing Tech Univ, Coll Chem Engn, State Key Lab Mat Oriented Chem Engn, Nanjing 210009, Peoples R China 3.Univ Manchester, Sch Engn, Dept Chem Engn & Analyt Sci, Manchester M13 9PL, Lancs, England 4.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Peoples R China 5.Univ Manchester, Sch Nat Sci, Dept Mat, Manchester, Lancs, England 6.Vidyasirimedhi Inst Sci & Technol, Sch Energy Sci & Engn, Rayong, Thailand 7.Vidyasirimedhi Inst Sci & Technol, Nanocatalysts & Nanomat Sustainable Energy & Envi, Rayong, Thailand |
| 推荐引用方式 GB/T 7714 | Chen, Huanhao,Shao, Yan,Mu, Yibing,et al. Structured silicalite-1 encapsulated Ni catalyst supported on SiC foam for dry reforming of methane[J]. AICHE JOURNAL,2020:15. |
| APA | Chen, Huanhao.,Shao, Yan.,Mu, Yibing.,Xiang, Huan.,Zhang, Rongxin.,...&Fan, Xiaolei.(2020).Structured silicalite-1 encapsulated Ni catalyst supported on SiC foam for dry reforming of methane.AICHE JOURNAL,15. |
| MLA | Chen, Huanhao,et al."Structured silicalite-1 encapsulated Ni catalyst supported on SiC foam for dry reforming of methane".AICHE JOURNAL (2020):15. |
入库方式： OAI收割
来源：金属研究所
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