Identification of the Reduction Reaction Mechanism of V3+ on a Graphite Electrode in Acidic Solutions
文献类型：期刊论文
| 作者 | Jing, Minghua1,2; Fang, Dawei2; Fan, Xinzhuang1,3; Liu, Jianguo1; Yan, Chuanwei1 |
| 刊名 | JOURNAL OF THE ELECTROCHEMICAL SOCIETY
 |
| 出版日期 | 2020-12-01 |
| 卷号 | 167期号:16页码:6 |
| 关键词 | Energy Storage Batteries aqueous Electrode Kinetics |
| ISSN号 | 0013-4651 |
| DOI | 10.1149/1945-7111/abd36d |
| 通讯作者 | Fan, Xinzhuang(mexzfan@gmail.com) |
| 英文摘要 | The oxidation and reduction reaction mechanisms of the VO2+/VO2+ redox couple have been studied to better understand the electrode reaction processes and further optimize the battery performance of vanadium flow battery (VFB) in our previous work. However, it is found that the negative electrode process of VFB plays a more important role in the improvement of the overall battery performance as research continues. Hence, the reduction reaction mechanism of V3+ in acidic solutions has been investigated systematacially in this work. Potentiodynamic polarization combined with rotating disk electrode have been applied to calculate the reaction orders (m) and the electron transfer number (n) of the reduction reaction of V3+. The results of this work demonstrated that the reduction reaction of V3+ is a single electron transfer step and H+ keeps out of the electrochemical reaction. Furthermore, the kinetic equation for the reduction reaction of V3+ has been established, and the theoretic polarization curve based on the established kinetic equation is well consistent with the experimental result, indicating an accurate prediction of the polarization behavior in V3+ acidic solutions. |
| 资助项目 | Natural Science Foundation of China[21703263] ; Open project of State Key Laboratory of Heavy Oil Processing in China University of Petroleum[Y7F1911191] ; Science and Technology Seedling Project of Liaoning Provincial education department[LQN201911] ; Youth Research Fund of Liaoning University[LDQN2019019] ; Doctoral Fund of Liaoning Provincial Department of Science and Technology[2020-BS-079] |
| WOS研究方向 | Electrochemistry ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000615207900001 |
| 出版者 | ELECTROCHEMICAL SOC INC |
| 资助机构 | Natural Science Foundation of China ; Open project of State Key Laboratory of Heavy Oil Processing in China University of Petroleum ; Science and Technology Seedling Project of Liaoning Provincial education department ; Youth Research Fund of Liaoning University ; Doctoral Fund of Liaoning Provincial Department of Science and Technology |
| 源URL | [http://ir.imr.ac.cn/handle/321006/159138]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Fan, Xinzhuang |
| 作者单位 | 1.Chinese Acad Sci, Inst Met Res, Liaoning Engn Res Ctr Adv Battery Mat, Shenyang 110016, Peoples R China 2.Liaoning Univ, Inst Rare & Scattered Elements, Coll Chem, Shenyang 110036, Peoples R China 3.Guangzhou HKUST Fok Ying Tung Res Inst, Bldg Energy Res Ctr, Guangzhou 511458, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jing, Minghua,Fang, Dawei,Fan, Xinzhuang,et al. Identification of the Reduction Reaction Mechanism of V3+ on a Graphite Electrode in Acidic Solutions[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY,2020,167(16):6. |
| APA | Jing, Minghua,Fang, Dawei,Fan, Xinzhuang,Liu, Jianguo,&Yan, Chuanwei.(2020).Identification of the Reduction Reaction Mechanism of V3+ on a Graphite Electrode in Acidic Solutions.JOURNAL OF THE ELECTROCHEMICAL SOCIETY,167(16),6. |
| MLA | Jing, Minghua,et al."Identification of the Reduction Reaction Mechanism of V3+ on a Graphite Electrode in Acidic Solutions".JOURNAL OF THE ELECTROCHEMICAL SOCIETY 167.16(2020):6. |
入库方式： OAI收割
来源：金属研究所
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