(MMP3O9)-M-I-P-II (M-I = Rb, M-II = Cd, Mg, Ca; M-I = Cs, M-II = Pb, Sr; M-I = K, M-II = Mg): Cation Substitution Application in Cyclophosphate Family and Nonlinear Optical Properties
文献类型：期刊论文
| 作者 | Abudoureheman, M (Abudoureheman, Maierhaba)[ 1,2 ]; Pan, XB (Pan, Xiaobo)[ 1 ]; Han, SJ (Han, Shujuan)[ 1 ] ; Rouzhahong, Y (Rouzhahong, Yilimiranmu)[ 1 ]; Yang, ZH (Yang, Zhihua)[ 1 ]; Wu, HP (Wu, Hongping)[ 1 ]; Pan, SL (Pan, Shilie)[ 1 ]
|
| 刊名 | INORGANIC CHEMISTRY
 |
| 出版日期 | 2018 |
| 卷号 | 57期号:12页码:7372-7379 |
| ISSN号 | 0020-1669 |
| DOI | 10.1021/acs.inorgchem.8b01017 |
| 英文摘要 | By the application of cation substitution, five new members of cyclophosphates, RbCdP3O9, CsPbP3O9, CsSrP3O9, RbMgP3O9, and RbCaP3O9, were obtained by a high-temperature melt method and structurally analyzed. The five compounds have identical stoichiometries, and all of them feature a three-dimensional network, which consists of (MO6)-O-II (M-II = Cd, Mg, Ca, Pb, Sr) octahedra and cyclic P3O9 units, while alkali-metal atoms are located within the network. However, RbCdP3O9 and CsPbP(3)O(9)belong to the asymmetric space groups P (6) over bar c2 and Pna2(1) respectively, and the other three compounds belong to orthorhombic space group Pnma. Detailed structure comparisons in the M-I-M-II-P-O and ((MMP3O9)-M-I-P-II)(n) (n = 1, 2, 6) systems are discussed. Remarkably, KMgP3O9 as one of the cyclophosphate members exhibits a second harmonic generation (SHG) intensity about 0.2 times that of KH2PO4 (KDP), RbCdP3O9, and CsPbP3O9 also show SHG responses 0.1 times that of KDP. In addition, the related optical properties are discussed. Furthermore, theoretical calculations and dipole moments were calculated to explain the relation of structure and optical properties. |
| WOS记录号 | WOS:000436023800066 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/5785]  |
| 专题 | 新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室 新疆理化技术研究所_材料物理与化学研究室 |
| 通讯作者 | Han, SJ (Han, Shujuan)[ 1 ]; Pan, SL (Pan, Shilie)[ 1 ] |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Key Lab Funct Mat & Devices Special Environm, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China |
| 推荐引用方式 GB/T 7714 | Abudoureheman, M ,Pan, XB ,Han, SJ ,et al. (MMP3O9)-M-I-P-II (M-I = Rb, M-II = Cd, Mg, Ca; M-I = Cs, M-II = Pb, Sr; M-I = K, M-II = Mg): Cation Substitution Application in Cyclophosphate Family and Nonlinear Optical Properties[J]. INORGANIC CHEMISTRY,2018,57(12):7372-7379. |
| APA | Abudoureheman, M .,Pan, XB .,Han, SJ .,Rouzhahong, Y .,Yang, ZH .,...&Pan, SL .(2018).(MMP3O9)-M-I-P-II (M-I = Rb, M-II = Cd, Mg, Ca; M-I = Cs, M-II = Pb, Sr; M-I = K, M-II = Mg): Cation Substitution Application in Cyclophosphate Family and Nonlinear Optical Properties.INORGANIC CHEMISTRY,57(12),7372-7379. |
| MLA | Abudoureheman, M ,et al."(MMP3O9)-M-I-P-II (M-I = Rb, M-II = Cd, Mg, Ca; M-I = Cs, M-II = Pb, Sr; M-I = K, M-II = Mg): Cation Substitution Application in Cyclophosphate Family and Nonlinear Optical Properties".INORGANIC CHEMISTRY 57.12(2018):7372-7379. |
入库方式： OAI收割
来源：新疆理化技术研究所
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。