SrTi(IO3)(6)center dot 2H(2)O and SrSn(IO3)(6): distinct arrangements of lone pair electrons leading to large birefringences
文献类型：期刊论文
| 作者 | Liu, KT (Liu, Kaitong)[ 1,2 ]; Han, J (Han, Jian)[ 1 ]; Huang, JB (Huang, Junben)[ 1 ]; Wei, ZL (Wei, Zhonglei)[ 1,2 ]; Yang, ZH (Yang, Zhihua)[ 1 ] ; Pan, SL (Pan, Shilie)[ 1 ]
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| 刊名 | RSC ADVANCES
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| 出版日期 | 2021 |
| 卷号 | 11期号:17页码:10309-10315 |
| ISSN号 | 2046-2069 |
| DOI | 10.1039/d0ra10726c |
| 英文摘要 | Three new iodates SrTi(IO3)(6)center dot 2H(2)O, (H3O)(2)Ti(IO3)(6), and SrSn(IO3)(6) have been synthesized via a facile hydrothermal method. The three compounds have zero-dimensional crystal structures composed of one [MO6](8-) (M = Ti, Sn) octahedron connected with six [IO3](-) trigonal pyramids. However, the particular coordination of Sr2+ cations results in distinct arrangements of lone pair electrons in an [IO3](-) trigonal pyramid, which leads to large birefringences. More importantly, this work enriches the species crystal chemistry for [M(IO3)(6)](2-) (M = Ti, Sn) clusters-containing iodates. |
| WOS记录号 | WOS:000629707400055 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/7803]  |
| 专题 | 新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室 新疆理化技术研究所_材料物理与化学研究室 |
| 通讯作者 | Han, J (Han, Jian)[ 1 ]; Pan, SL (Pan, Shilie)[ 1 ] |
| 作者单位 | 1.Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, CAS Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, KT ,Han, J ,Huang, JB ,et al. SrTi(IO3)(6)center dot 2H(2)O and SrSn(IO3)(6): distinct arrangements of lone pair electrons leading to large birefringences[J]. RSC ADVANCES,2021,11(17):10309-10315. |
| APA | Liu, KT ,Han, J ,Huang, JB ,Wei, ZL ,Yang, ZH ,&Pan, SL .(2021).SrTi(IO3)(6)center dot 2H(2)O and SrSn(IO3)(6): distinct arrangements of lone pair electrons leading to large birefringences.RSC ADVANCES,11(17),10309-10315. |
| MLA | Liu, KT ,et al."SrTi(IO3)(6)center dot 2H(2)O and SrSn(IO3)(6): distinct arrangements of lone pair electrons leading to large birefringences".RSC ADVANCES 11.17(2021):10309-10315. |
入库方式： OAI收割
来源：新疆理化技术研究所
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