Structural and electrical properties of Ca-doped Co1.5-xCaxMn1.2Ni0.3O4 (0 <= x <= 0.8) NTC ceramics
文献类型：期刊论文
| 作者 | Ma, XH (Ma, Xiuhua)[ 1,2,3,4 ]; Zhang, HM (Zhang, Huimin)[ 1,2,4 ] ; Li, HB (Li, Haibing)[ 1,2,4 ]; Ma, PF (Ma, Panfei)[ 1,2 ]; Jiang, H (Jiang, Hui)[ 1,2 ]; Chang, AM (Chang, Aimin)[ 1,2,4 ]
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| 刊名 | JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
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| 出版日期 | 2021 |
| 卷号 | 32期号:5页码:5849-5858 |
| ISSN号 | 0957-4522 |
| DOI | 10.1007/s10854-021-05305-x |
| 英文摘要 | The influence of Ca content on the morphology and related electrical properties of Co1.5-xCaxMn1.2Ni0.3O4 (x = 0, 0.2, 0.4, 0.8) ceramics was studied. Appropriate addition of Ca will reduce the grain size, but when the content of Ca is 0.4, the holes will appear on the surface. As the Ca content of Co1.5-xCaxMn1.2Ni0.3O4 increases from 0 to 0.8, the temperature-dependent resistivity (rho(25)) decreases from 1291.5 to 180.8 omega cm, and the value of B-25/50 decreases from 3860 to 3077 K. This is because the addition of Ca ions promotes the valence conversion of Mn3+ ions to Mn4+ ions, reduces the ratio of Mn3+/Mn4+, and thereby reduces the resistivity. The results show that when the Ca content is 0.4, the material has small grain size, low resistivity, and B value. It can be used as a NTC thermistor potential candidate materials in the temperature range of 223 K to 323 K. |
| WOS记录号 | WOS:000613613400003 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/7804]  |
| 专题 | 新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室 新疆理化技术研究所_材料物理与化学研究室 |
| 通讯作者 | Zhang, HM (Zhang, Huimin)[ 1,2,4 ]; Chang, AM (Chang, Aimin)[ 1,2,4 ] |
| 作者单位 | 1.Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China 4.Chinese Acad Sci, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ma, XH ,Zhang, HM ,Li, HB ,et al. Structural and electrical properties of Ca-doped Co1.5-xCaxMn1.2Ni0.3O4 (0 <= x <= 0.8) NTC ceramics[J]. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS,2021,32(5):5849-5858. |
| APA | Ma, XH ,Zhang, HM ,Li, HB ,Ma, PF ,Jiang, H ,&Chang, AM .(2021).Structural and electrical properties of Ca-doped Co1.5-xCaxMn1.2Ni0.3O4 (0 <= x <= 0.8) NTC ceramics.JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS,32(5),5849-5858. |
| MLA | Ma, XH ,et al."Structural and electrical properties of Ca-doped Co1.5-xCaxMn1.2Ni0.3O4 (0 <= x <= 0.8) NTC ceramics".JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS 32.5(2021):5849-5858. |
入库方式： OAI收割
来源：新疆理化技术研究所
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