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Fabrication of hypercrosslinked hydroxyl-rich solid phase extractants for cesium separation from the salt lake brine

文献类型：期刊论文

作者Xu, Zihao2,3; Rong, Meng2,3; Meng, Qiyu2,3; Yao, Haoyu1,2; Ni, Shan2,3; Wang, Li3; Xing, Huifang2,3; Qu, Hongnan3; Yang, Liangrong2,3; Liu, Huizhou2,3
刊名CHEMICAL ENGINEERING JOURNAL
出版日期2020-11-15
卷号400页码:12
关键词Phenols Solid phase extractants Ion exchange Cesium Salt lake brine
ISSN号1385-8947
DOI10.1016/j.cej.2020.125991
英文摘要In this work, two hypercrosslinked hydroxyl-rich polymers (HCP-P and HCP-R) were facilely prepared through a one-pot Friedel-Crafts polymerization of phenol, resorcinol and formaldehyde dimethyl acetal, respectively. HCP-P and HCP-R were investigated for their ability to separate Cs+ from the salt lake brine via ion-exchange reaction between Cs+ and O- Na+. The Cs+ adsorption isotherms of HCP-P and HCP-R follow the Langmuir model, and their adsorption capacities reach 249.64 mg g(-1) and 259.97 mg g(-1), surpassing most of commercial materials like AMP-PAN (81 mg g(-1)) and TAM-5 (191.8 mg g(-1)). The Cs+/K+ separation factors (S.F.) of HCPs can reach 12.4 even in the presence of high concentrations of K+ (C-(K)(+)/C-(Cs)(+) = 712.5). Notably, HCPs could retain more than 90% of the adsorption capacities after 5 successive adsorption-desorption cycles. Besides, X-ray photoelectron spectroscopy (XPS), FT-IR spectra and TEM-EDS analysis revealed the ion exchange mechanism of the Cs+ adsorption process. This work demonstrated the excellent application potential of hypercrosslinked hydroxyl-rich polymer adsorbents in separating Cs+ from the salt lake brine.
WOS关键词ION-EXCHANGE ; SOLVENT-EXTRACTION ; AMMONIUM MOLYBDOPHOSPHATE ; AQUEOUS-SOLUTIONS ; SELECTIVE REMOVAL ; ALKALI-METALS ; ADSORPTION ; WASTE ; STRONTIUM ; CS+
资助项目National Natural Science Foundation of China[21922814] ; National Natural Science Foundation of China[21676273] ; National Natural Science Foundation of China[21961160745] ; National Natural Science Foundation of China[31961133019] ; National Natural Science Foundation of China[21921005] ; Beijing Natural Science Foundation[2194086]
WOS研究方向Engineering
语种英语
WOS记录号WOS:000569320400006
出版者ELSEVIER SCIENCE SA
资助机构National Natural Science Foundation of China ; Beijing Natural Science Foundation
源URL[http://ir.ipe.ac.cn/handle/122111/42103]  
专题中国科学院过程工程研究所
通讯作者Yang, Liangrong; Liu, Huizhou
作者单位1.Chinese Acad Sci, Beijing Key Lab Ionic Liquids Clean Proc, Key Lab Green Proc & Engn, Inst Proc Engn, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Sch Chem Engn, Beijing 100049, Peoples R China
3.Chinese Acad Sci, Key Lab Green Proc & Engn, State Key Lab Biochem Engn, Inst Proc Engn, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714		 Xu, Zihao,Rong, Meng,Meng, Qiyu,et al. Fabrication of hypercrosslinked hydroxyl-rich solid phase extractants for cesium separation from the salt lake brine[J]. CHEMICAL ENGINEERING JOURNAL,2020,400:12.
APA Xu, Zihao.,Rong, Meng.,Meng, Qiyu.,Yao, Haoyu.,Ni, Shan.,...&Liu, Huizhou.(2020).Fabrication of hypercrosslinked hydroxyl-rich solid phase extractants for cesium separation from the salt lake brine.CHEMICAL ENGINEERING JOURNAL,400,12.
MLA Xu, Zihao,et al."Fabrication of hypercrosslinked hydroxyl-rich solid phase extractants for cesium separation from the salt lake brine".CHEMICAL ENGINEERING JOURNAL 400(2020):12.

入库方式： OAI收割

来源：过程工程研究所

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