中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Easily Synthesized Ru Catalyst Efficiently Converts Carbonyl Compounds and Ammonia into Primary Amines

文献类型:期刊论文

作者Pan, Jia-Sheng2,3; Zhang, Rui2; Ma, Shuang-Shuang1,3; Han, Li-Jun3; Xu, Bao-Hua1,3
刊名CHEMISTRYSELECT
出版日期2020-09-22
卷号5期号:35页码:10933-10938
关键词Homogeneous catalysis Primary amines Reductive amination Ruthenium
ISSN号2365-6549
DOI10.1002/slct.202002795
英文摘要An easily synthesized ruthenium(II) complex was developed for the direct reductive amination of both aldehydes and ketones with H(2)and ammonia. The intramolecular carboxylate-assisted hydrogenation fashion was found compatible with the amination between carbonyl substrates and ammonia, enabling a high selectivity toward primary amines. Varied primary amines were obtained with a turnover numbers (TON) up to 376.
WOS关键词ALKYL-ARYL KETONES ; REDUCTIVE AMINATION ; GENERAL-SYNTHESIS ; ASYMMETRIC HYDROGENATION ; SELECTIVE SYNTHESIS ; AQUEOUS AMMONIA ; N-ALKYLATION ; COMPLEXES ; ALCOHOLS ; NITRILES
资助项目National Natural Science Foundation of China (Petrochemical Joint Fund)[U1662133] ; National Natural Science Foundation of China (Petrochemical Joint Fund)[21374029] ; Key Research Program of Frontier Sciences, CAS[ZDBS-LY-JSC022] ; Zhengzhou High Level Talent Certificate[20180200052] ; K. C. Wong Education Foundation[GJTD-2018-04]
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000571508100014
出版者WILEY-V C H VERLAG GMBH
资助机构National Natural Science Foundation of China (Petrochemical Joint Fund) ; Key Research Program of Frontier Sciences, CAS ; Zhengzhou High Level Talent Certificate ; K. C. Wong Education Foundation
源URL[http://ir.ipe.ac.cn/handle/122111/42173]  
专题中国科学院过程工程研究所
通讯作者Zhang, Rui; Xu, Bao-Hua
作者单位1.Univ Chinese Acad Sci, Coll Chem & Chem Engn, Beijing 100190, Peoples R China
2.East China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China
3.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, Key Lab Green Proc & Engn, State Key Lab Multiphase Complex Syst,Inst Proc E, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Pan, Jia-Sheng,Zhang, Rui,Ma, Shuang-Shuang,et al. Easily Synthesized Ru Catalyst Efficiently Converts Carbonyl Compounds and Ammonia into Primary Amines[J]. CHEMISTRYSELECT,2020,5(35):10933-10938.
APA Pan, Jia-Sheng,Zhang, Rui,Ma, Shuang-Shuang,Han, Li-Jun,&Xu, Bao-Hua.(2020).Easily Synthesized Ru Catalyst Efficiently Converts Carbonyl Compounds and Ammonia into Primary Amines.CHEMISTRYSELECT,5(35),10933-10938.
MLA Pan, Jia-Sheng,et al."Easily Synthesized Ru Catalyst Efficiently Converts Carbonyl Compounds and Ammonia into Primary Amines".CHEMISTRYSELECT 5.35(2020):10933-10938.

入库方式: OAI收割

来源:过程工程研究所

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