Easily Synthesized Ru Catalyst Efficiently Converts Carbonyl Compounds and Ammonia into Primary Amines
文献类型:期刊论文
作者 | Pan, Jia-Sheng2,3; Zhang, Rui2; Ma, Shuang-Shuang1,3; Han, Li-Jun3; Xu, Bao-Hua1,3 |
刊名 | CHEMISTRYSELECT
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出版日期 | 2020-09-22 |
卷号 | 5期号:35页码:10933-10938 |
关键词 | Homogeneous catalysis Primary amines Reductive amination Ruthenium |
ISSN号 | 2365-6549 |
DOI | 10.1002/slct.202002795 |
英文摘要 | An easily synthesized ruthenium(II) complex was developed for the direct reductive amination of both aldehydes and ketones with H(2)and ammonia. The intramolecular carboxylate-assisted hydrogenation fashion was found compatible with the amination between carbonyl substrates and ammonia, enabling a high selectivity toward primary amines. Varied primary amines were obtained with a turnover numbers (TON) up to 376. |
WOS关键词 | ALKYL-ARYL KETONES ; REDUCTIVE AMINATION ; GENERAL-SYNTHESIS ; ASYMMETRIC HYDROGENATION ; SELECTIVE SYNTHESIS ; AQUEOUS AMMONIA ; N-ALKYLATION ; COMPLEXES ; ALCOHOLS ; NITRILES |
资助项目 | National Natural Science Foundation of China (Petrochemical Joint Fund)[U1662133] ; National Natural Science Foundation of China (Petrochemical Joint Fund)[21374029] ; Key Research Program of Frontier Sciences, CAS[ZDBS-LY-JSC022] ; Zhengzhou High Level Talent Certificate[20180200052] ; K. C. Wong Education Foundation[GJTD-2018-04] |
WOS研究方向 | Chemistry |
语种 | 英语 |
WOS记录号 | WOS:000571508100014 |
出版者 | WILEY-V C H VERLAG GMBH |
资助机构 | National Natural Science Foundation of China (Petrochemical Joint Fund) ; Key Research Program of Frontier Sciences, CAS ; Zhengzhou High Level Talent Certificate ; K. C. Wong Education Foundation |
源URL | [http://ir.ipe.ac.cn/handle/122111/42173] ![]() |
专题 | 中国科学院过程工程研究所 |
通讯作者 | Zhang, Rui; Xu, Bao-Hua |
作者单位 | 1.Univ Chinese Acad Sci, Coll Chem & Chem Engn, Beijing 100190, Peoples R China 2.East China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China 3.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, Key Lab Green Proc & Engn, State Key Lab Multiphase Complex Syst,Inst Proc E, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Pan, Jia-Sheng,Zhang, Rui,Ma, Shuang-Shuang,et al. Easily Synthesized Ru Catalyst Efficiently Converts Carbonyl Compounds and Ammonia into Primary Amines[J]. CHEMISTRYSELECT,2020,5(35):10933-10938. |
APA | Pan, Jia-Sheng,Zhang, Rui,Ma, Shuang-Shuang,Han, Li-Jun,&Xu, Bao-Hua.(2020).Easily Synthesized Ru Catalyst Efficiently Converts Carbonyl Compounds and Ammonia into Primary Amines.CHEMISTRYSELECT,5(35),10933-10938. |
MLA | Pan, Jia-Sheng,et al."Easily Synthesized Ru Catalyst Efficiently Converts Carbonyl Compounds and Ammonia into Primary Amines".CHEMISTRYSELECT 5.35(2020):10933-10938. |
入库方式: OAI收割
来源:过程工程研究所
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