Curing behaviors and properties of epoxy resins with para-hexatomic ring blocks: Excellent comprehensive performances of tetrafluorophenyl
文献类型：期刊论文
| 作者 | Ma, Tian2; Ma, Jiahao2; Zhang, Junying2; Cheng, Jue2; Yang, Chao1 |
| 刊名 | POLYMER
 |
| 出版日期 | 2020-10-07 |
| 卷号 | 206页码:10 |
| 关键词 | Excellent comprehensive performances Tetrafluorophenyl Para-hexatomic ring Non-isothermal curing kinetics Hydrophobicity Low permittivity |
| ISSN号 | 0032-3861 |
| DOI | 10.1016/j.polymer.2020.122828 |
| 英文摘要 | It is a longstanding bottleneck for epoxies applied in high-tech fields to obtain integrated performances, including excellent thermal mechanical and stability properties, hydrophobicity, low permittivity and curing activation energy. A novel epoxy monomer with stiff tetrafluorophenyl backbone and robust intramolecular/intermolecular forces is expected to fundamentally break through this challenge. Herein, three model epoxy monomers with different symmetrical para-hexatomic ring blocks were synthesized, including tetrafluorophenyl-based (FEP), phenyl-based (TEREP) and cyclohexyl-based (CEP), followed by curing with methylhexahydrophthalic anhydride (MeHHPA) and polyetheramine (D230), respectively. As expected, TEREP showed better thermal mechanical properties than CEP due to closer stacking density and electronic effect. Noticeably, FEP self-consistently showed the best comprehensive properties among three resins, which mainly benefited from the introduced C-F bonds and the unique electronic effect caused by tetrafluorophenyl. Moreover, the exhilarating results of tetrafluorophenyl para-hexatomic ring provide an efficient guideline for building epoxy-based material genomes to better design future-oriented engineering materials. |
| WOS关键词 | REDUCED GRAPHENE OXIDE ; BISPHENOL-A ; MECHANICAL-PROPERTIES ; DIELECTRIC-CONSTANT ; DIGLYCIDYL ETHER ; T-G ; FLUORINE ; POLYMERIZATION ; NANOCOMPOSITES ; COMPOSITES |
| 资助项目 | National Key Research Program[2016YFB0302000] |
| WOS研究方向 | Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000576842800009 |
| 出版者 | ELSEVIER SCI LTD |
| 资助机构 | National Key Research Program |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/42320]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Cheng, Jue; Yang, Chao |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China 2.Beijing Univ Chem Technol, Key Lab Carbon Fiber & Funct Polymers, Minist Educ, Beijing 100029, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ma, Tian,Ma, Jiahao,Zhang, Junying,et al. Curing behaviors and properties of epoxy resins with para-hexatomic ring blocks: Excellent comprehensive performances of tetrafluorophenyl[J]. POLYMER,2020,206:10. |
| APA | Ma, Tian,Ma, Jiahao,Zhang, Junying,Cheng, Jue,&Yang, Chao.(2020).Curing behaviors and properties of epoxy resins with para-hexatomic ring blocks: Excellent comprehensive performances of tetrafluorophenyl.POLYMER,206,10. |
| MLA | Ma, Tian,et al."Curing behaviors and properties of epoxy resins with para-hexatomic ring blocks: Excellent comprehensive performances of tetrafluorophenyl".POLYMER 206(2020):10. |
入库方式： OAI收割
来源：过程工程研究所
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