Excess spectroscopy and its applications in the study of solution chemistry
文献类型：期刊论文
| 作者 | Zhang, Yaqin1; Wu, Zhiwei1; Wang, Yaqian2; He, Hongyan1; Yu, Zhiwu2 |
| 刊名 | PURE AND APPLIED CHEMISTRY
 |
| 出版日期 | 2020-10-01 |
| 卷号 | 92期号:10页码:1611-1626 |
| 关键词 | excess spectroscopy hydrogen bond ICSC-36 ionic liquid micro heterogeneity solution structure |
| ISSN号 | 0033-4545 |
| DOI | 10.1515/pac-2020-0107 |
| 英文摘要 | Characterization of structural heterogeneity of liquid solutions and the pursuit of its nature have been challenging tasks to solution chemists. In the last decade, an emerging method called excess spectroscopy has found applications in this area. The method, combining the merits of molecular spectroscopy and excess thermodynamic functions, shows the ability to enhance the apparent resolution of spectra, provides abundant information concerning solution structures and intermolecular interactions. In this review, the thinking and mathematics of the method, as well as its developments, are presented first. Then, research progress related to the exploration of the method is thoroughly reviewed. The materials are classified into two parts, small-molecular solutions and ionic liquid solutions. Finally, potential challenges and the perspective for further development of the method are discussed. |
| WOS关键词 | HYDROGEN-BONDING INTERACTIONS ; IONIC LIQUID ; BINARY-MIXTURES ; DIMETHYL-SULFOXIDE ; MOLECULAR-DYNAMICS ; ALIPHATIC-ALCOHOLS ; WATER ; MICROHETEROGENEITY ; ACETONITRILE ; SYSTEMS |
| 资助项目 | National Science Fund for Excellent Young Scholars[21922813] ; National Natural Science Foundation of China[21733011] ; National Natural Science Foundation of China[21834006] ; Youth Innovation Promotion Association of CAS[2017066] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000580659100008 |
| 出版者 | WALTER DE GRUYTER GMBH |
| 资助机构 | National Science Fund for Excellent Young Scholars ; National Natural Science Foundation of China ; Youth Innovation Promotion Association of CAS |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/42454]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | He, Hongyan; Yu, Zhiwu |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Beijing Key Lab Ion Liquids Clean Proc, CAS Key Lab Green Proc & Engn,State Key Lab Multi, Beijing 100190, Peoples R China 2.Tsinghua Univ, Dept Chem, MOE Key Lab Bioorgan Phosphorous Chem & Chem Biol, Beijing 100084, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Yaqin,Wu, Zhiwei,Wang, Yaqian,et al. Excess spectroscopy and its applications in the study of solution chemistry[J]. PURE AND APPLIED CHEMISTRY,2020,92(10):1611-1626. |
| APA | Zhang, Yaqin,Wu, Zhiwei,Wang, Yaqian,He, Hongyan,&Yu, Zhiwu.(2020).Excess spectroscopy and its applications in the study of solution chemistry.PURE AND APPLIED CHEMISTRY,92(10),1611-1626. |
| MLA | Zhang, Yaqin,et al."Excess spectroscopy and its applications in the study of solution chemistry".PURE AND APPLIED CHEMISTRY 92.10(2020):1611-1626. |
入库方式： OAI收割
来源：过程工程研究所
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