Crystal Facet Engineering of Single-Crystalline TiC Nanocubes for Improved Hydrogen Evolution Reaction
文献类型：期刊论文
| 作者 | Song, Miao2,3,4; Chen, Dehong1; Yang, Yafeng3,4; Xiang, Maoqiao4,5; Zhu, Qingshan3,4; Zhao, Hongdan3,4; Ward, Liam2; Chen, Xiao-Bo2 |
| 刊名 | ADVANCED FUNCTIONAL MATERIALS
 |
| 出版日期 | 2020-11-03 |
| 页码 | 6 |
| ISSN号 | 1616-301X |
| 关键词 | {100} facets hydrogen evolution reaction single‐ crystalline titanium carbide |
| DOI | 10.1002/adfm.202008028 |
| 英文摘要 | Single-crystalline {100} faceted TiC is of great significance in theory to a large number of engineering applications owing to its extraordinary catalytic properties. However, the {111} planes are prevalent in conventional TiC powders given their favorable thermodynamic stability during the initial low stoichiometric growth stage. Herein, a disproportionation-decomposition strategy is developed to directly produce Ti and C atoms to synthesize single-crystalline {100} faceted TiC powders. Outstanding electrochemical performance of TiC {100} crystal planes in terms of the hydrogen evolution reaction is evidenced by an overpotential of 392 mV at 10 mA cm(-2), which is 52% lower than that of randomly faceted TiC counterparts (815 mV). |
| WOS关键词 | TITANIUM CARBIDE ; LOW-TEMPERATURE ; CARBON ; EFFICIENT ; PERCENTAGE ; MORPHOLOGY ; NANOSHEETS ; REDUCTION ; SURFACE ; MXENE |
| 资助项目 | Bureau of Frontier Sciences and Education, Chinese Academy of Sciences[ZDBS-LY-JSC041] ; National Natural Science Foundation of China[11805227] ; Key Research Program of Nanjing IPE Institute of Green Manufacturing Industry[E0010708] ; China Scholarship Council[201904910825] ; Innovation Academy for Green Manufacture, Chinese Academy of Sciences[IAGM-2019-A11] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| 语种 | 英语 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| WOS记录号 | WOS:000584077600001 |
| 资助机构 | Bureau of Frontier Sciences and Education, Chinese Academy of Sciences ; National Natural Science Foundation of China ; Key Research Program of Nanjing IPE Institute of Green Manufacturing Industry ; China Scholarship Council ; Innovation Academy for Green Manufacture, Chinese Academy of Sciences |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/42496]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Xiang, Maoqiao; Zhu, Qingshan |
| 作者单位 | 1.RMIT Univ, Sch Sci, 124 La Trobe St, Melbourne, Vic 3001, Australia 2.RMIT Univ, Sch Engn, 124 La Trobe St, Melbourne, Vic 3001, Australia 3.Univ Chinese Acad Sci, Sch Chem Engn, 19 Yuquan Rd, Beijing 100049, Peoples R China 4.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, 1 North Second St, Beijing 100190, Peoples R China 5.Nanjing IPE Inst Green Mfg Ind, 266 Chuangyan Rd, Nanjing 211135, Peoples R China |
| 推荐引用方式 GB/T 7714 | Song, Miao,Chen, Dehong,Yang, Yafeng,et al. Crystal Facet Engineering of Single-Crystalline TiC Nanocubes for Improved Hydrogen Evolution Reaction[J]. ADVANCED FUNCTIONAL MATERIALS,2020:6. |
| APA | Song, Miao.,Chen, Dehong.,Yang, Yafeng.,Xiang, Maoqiao.,Zhu, Qingshan.,...&Chen, Xiao-Bo.(2020).Crystal Facet Engineering of Single-Crystalline TiC Nanocubes for Improved Hydrogen Evolution Reaction.ADVANCED FUNCTIONAL MATERIALS,6. |
| MLA | Song, Miao,et al."Crystal Facet Engineering of Single-Crystalline TiC Nanocubes for Improved Hydrogen Evolution Reaction".ADVANCED FUNCTIONAL MATERIALS (2020):6. |
入库方式： OAI收割
来源：过程工程研究所
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