Conversion of palmitic acid to jet fuel components over Mo/H-ZSM-22 bi-functional catalysts with high carbon reservation
文献类型：期刊论文
| 作者 | Zhang, Jimei1,3; Shi, Yanchun3; Cao, Hongbin3; Wu, Yulong2; Yang, Mingde2 |
| 刊名 | APPLIED CATALYSIS A-GENERAL
 |
| 出版日期 | 2020-11-25 |
| 卷号 | 608页码:10 |
| 关键词 | Mo/H-ZSM-22 Palmitic acid Hydrodeoxygenation Isomerization |
| ISSN号 | 0926-860X |
| DOI | 10.1016/j.apcata.2020.117847 |
| 英文摘要 | The optimal preparation conditions of Mo/H-ZSM-22 bi-functional catalysts were obtained via the sublimation phenomenon of MoO3 at high calcination temperatures, which was beneficial for the well-dispersion of MoOx species with 5-10 nm particles. High reduction temperature enhanced the reduction from Mo6+ to Mo4+ and even from Mo4+ to Mo, which would be beneficial for iso-alkanes formation with higher carbon reservation. Importantly, 89.3 % selectivity of C-16 alkanes of which 61.7 % were iso-C-16 alkanes were obtained with complete deoxygenation of palmitic acid, which was the highest selectivity of C-16 alkanes over Mo/H-ZSM-22 bi-functional catalyst prepared at a calcination temperature of 550 degrees C and at a reduction temperature of 600 degrees C. The results would offer a novel candidate of bi-functional catalysts for upgrading of microalgae-based bio-oil to high value jet fuel components with high selectivity of iso-alkanes and carbon reservation. |
| WOS关键词 | ACTIVATED CARBON ; MICROALGAE OIL ; RAPESEED OIL ; STEARIC-ACID ; FATTY-ACIDS ; NI ; HYDRODEOXYGENATION ; DEOXYGENATION ; DIESEL ; MO |
| 资助项目 | National Science Foundation of China[21838006] ; National Science Foundation of China[21776159] ; National Science Foundation of China[21576155] |
| WOS研究方向 | Chemistry ; Environmental Sciences & Ecology |
| 语种 | 英语 |
| WOS记录号 | WOS:000592362200002 |
| 出版者 | ELSEVIER |
| 资助机构 | National Science Foundation of China |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/42689]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Shi, Yanchun; Wu, Yulong |
| 作者单位 | 1.Tianjin Univ, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China 2.Tsinghua Univ, Inst Nucl & New Energy Technol, Beijing 100084, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, CAS Key Lab Green Proc & Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Jimei,Shi, Yanchun,Cao, Hongbin,et al. Conversion of palmitic acid to jet fuel components over Mo/H-ZSM-22 bi-functional catalysts with high carbon reservation[J]. APPLIED CATALYSIS A-GENERAL,2020,608:10. |
| APA | Zhang, Jimei,Shi, Yanchun,Cao, Hongbin,Wu, Yulong,&Yang, Mingde.(2020).Conversion of palmitic acid to jet fuel components over Mo/H-ZSM-22 bi-functional catalysts with high carbon reservation.APPLIED CATALYSIS A-GENERAL,608,10. |
| MLA | Zhang, Jimei,et al."Conversion of palmitic acid to jet fuel components over Mo/H-ZSM-22 bi-functional catalysts with high carbon reservation".APPLIED CATALYSIS A-GENERAL 608(2020):10. |
入库方式： OAI收割
来源：过程工程研究所
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