O-3 oxidation excited by yellow phosphorus emulsion coupling with red mud absorption for denitration
文献类型:期刊论文
作者 | Li, Bin3; Liu, Yu3; Zhao, Xingting3; Ning, Ping3; Liu, Xiaolong2; Zhu, Tingyu1,2 |
刊名 | JOURNAL OF HAZARDOUS MATERIALS
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出版日期 | 2021-02-05 |
卷号 | 403页码:13 |
关键词 | Yellow phosphorus Ozone Red mud Denitration |
ISSN号 | 0304-3894 |
DOI | 10.1016/j.jhazmat.2020.123971 |
英文摘要 | Directing to unwieldiness NOx emitted by the industry, the removal of NOx was implemented using yellow phosphorus (P-4) emulsion and red mud slurry as composite absorbent. Where yellow phosphorus is considered to stimulate formation of the ecological ozone (O-3) from O-2, the oxidation of insoluble NO into water-soluble NOx species by O-3, and the red mud as a pH buffer can be used to maintain the pH of the absorption liquid in a range that better absorbs NOx. NO is finally converted into NO2- and NO3-, whereas the yellow phosphorus is mainly PO43- . Single-factor influencing on the efficiency of denitration include the concentration of yellow phosphorus, reaction temperature, stirring intensity, gas flow rate, O-2 content, and red mud solid-liquid ratio were investigated. Response surface methodology (RSM) was used to optimize the process parameters. It was indicated that the removal rate of NOx can reach 99.3% under the optimal conditions. Moreover, the possible denitration reaction mechanism was also discussed. |
WOS关键词 | FLUE-GAS ; SIMULTANEOUS REMOVAL ; EFFICIENT REMOVAL ; NO ; SO2 ; NITROGEN ; NANOCOMPOSITE ; REDUCTION ; NH3 |
资助项目 | Ministry of Science and Technoiogy of the People's Republic of China, National Key Research and Development Program of China[2019YFC0214404] ; Ministry of Science and Technoiogy of the People's Republic of China, National Key Research and Development Program of China[2017YFC0210500] ; Ministry of Science and Technoiogy of the People's Republic of China, National Key Research and Development Program of China[2017YFC0210600] |
WOS研究方向 | Engineering ; Environmental Sciences & Ecology |
语种 | 英语 |
WOS记录号 | WOS:000595080500001 |
出版者 | ELSEVIER |
资助机构 | Ministry of Science and Technoiogy of the People's Republic of China, National Key Research and Development Program of China |
源URL | [http://ir.ipe.ac.cn/handle/122111/42709] ![]() |
专题 | 中国科学院过程工程研究所 |
通讯作者 | Ning, Ping; Liu, Xiaolong |
作者单位 | 1.Chinese Acad Sci, Inst Urban Environm, Ctr Excellence Reg Atmospher Environm, Xiamen 361021, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydrometallurg Cleaner Prod, Beijing Engn Res Ctr Proc Pollut Control, Beijing 100190, Peoples R China 3.Kunming Univ Sci & Technol, Fac Environm Sci & Engn, Kunming 650500, Yunnan, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Bin,Liu, Yu,Zhao, Xingting,et al. O-3 oxidation excited by yellow phosphorus emulsion coupling with red mud absorption for denitration[J]. JOURNAL OF HAZARDOUS MATERIALS,2021,403:13. |
APA | Li, Bin,Liu, Yu,Zhao, Xingting,Ning, Ping,Liu, Xiaolong,&Zhu, Tingyu.(2021).O-3 oxidation excited by yellow phosphorus emulsion coupling with red mud absorption for denitration.JOURNAL OF HAZARDOUS MATERIALS,403,13. |
MLA | Li, Bin,et al."O-3 oxidation excited by yellow phosphorus emulsion coupling with red mud absorption for denitration".JOURNAL OF HAZARDOUS MATERIALS 403(2021):13. |
入库方式: OAI收割
来源:过程工程研究所
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