Regulating and regenerating the valuable metals from the cathode materials in lithium-ion batteries by nickel-cobalt-manganese co-extraction
文献类型：期刊论文
| 作者 | Liu, Tianchi1,3; Chen, Ji1,3; Shen, Xing2; Li, Hailian1 |
| 刊名 | SEPARATION AND PURIFICATION TECHNOLOGY
 |
| 出版日期 | 2021-03-15 |
| 卷号 | 259页码:9 |
| 关键词 | Co-extraction P227 Cathode material Regulation Regeneration |
| ISSN号 | 1383-5866 |
| DOI | 10.1016/j.seppur.2020.118088 |
| 英文摘要 | Effective recycling of valuable metals from the spent lithium-ion batteries (LIBs) is conducive to the rational utilization of resources and environmental protection. To shorten the recovery process and directly obtain the high-pure regenerated products, solvent extraction (co-extraction) method was employed in this work. Here, 3 mol/L (M) hydrochloride (HCl) without reductant was used as leaching agent for the leaching of cathode material, resulting in the leaching efficiency of all metals exceeding 99%. Subsequently, di-(2-ethylhexyl) phosphinic acid (P227) was used to co-extract transition metals directly from the leachate and separate them from lithium (Li). The composition of nickel (Ni), cobalt (Co), and manganese (Mn) extracted into the organic phase can be controlled by changing the extraction conditions, and the type of the cathode material was also regulated simultaneously. Finally, the loaded organic phase with a Ni-Co-Mn ratio of 1:1:1 was completely stripping with 0.4 M HCl, and the LiNi1/3Co1/3Mn1/3O2 was regenerated by oxalic acid co-precipitation the stripping solution and high temperature calcination. The regenerated LiNi1/3Co1/3Mn1/3O2 exhibits excellent electrochemical performance with 150.0 mA h g(-1) discharge capacity at 0.5 C. Therefore, the demonstrated separation and preparation integration process not only realizes the regeneration of the battery but also promotes the co-extraction technique to practical application. |
| WOS关键词 | SPENT LITHIUM ; PART II ; RECOVERY ; LINI1/3CO1/3MN1/3O2 ; SEPARATION ; EXTRACTION |
| 资助项目 | National Basic Research Program of China[2012CBA01202] ; Natural Science Foundation of China[51174184] ; Key Program of the Chinese Academy of Science[ZDRW-CN-2020-1] ; Key Program of the Chinese Academy of Science[KGZD-EW-201-1] |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000605005600002 |
| 出版者 | ELSEVIER |
| 资助机构 | National Basic Research Program of China ; Natural Science Foundation of China ; Key Program of the Chinese Academy of Science |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/43033]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Chen, Ji |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resources Utilizat, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, CAS Key Lab Green Proc Engn, State Key Lab Biochem Engn, Beijing 100190, Peoples R China 3.Univ Sci & Technol China, Hefei 230026, Anhui, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Tianchi,Chen, Ji,Shen, Xing,et al. Regulating and regenerating the valuable metals from the cathode materials in lithium-ion batteries by nickel-cobalt-manganese co-extraction[J]. SEPARATION AND PURIFICATION TECHNOLOGY,2021,259:9. |
| APA | Liu, Tianchi,Chen, Ji,Shen, Xing,&Li, Hailian.(2021).Regulating and regenerating the valuable metals from the cathode materials in lithium-ion batteries by nickel-cobalt-manganese co-extraction.SEPARATION AND PURIFICATION TECHNOLOGY,259,9. |
| MLA | Liu, Tianchi,et al."Regulating and regenerating the valuable metals from the cathode materials in lithium-ion batteries by nickel-cobalt-manganese co-extraction".SEPARATION AND PURIFICATION TECHNOLOGY 259(2021):9. |
入库方式： OAI收割
来源：过程工程研究所
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