Cobalt-Doped NiS2 Micro/Nanostructures with Complete Solid Solubility as High-Performance Cathode Materials for Actual High-Specific-Energy Thermal Batteries
文献类型：期刊论文
| 作者 | Guo, Hao2,3; Tang, Licheng2,4; Tian, Qianqiu1; Chu, Ying5; Shi, Bin2; Yin, Xucai3; Huo, Hua3; Han, Xiaopeng1; Yang, Chengxiang2; Wang, Chu2 |
| 刊名 | ACS APPLIED MATERIALS & INTERFACES
 |
| 出版日期 | 2020-11-11 |
| 卷号 | 12期号:45页码:50377-50387 |
| 关键词 | thermal batteries Ni1-xCoxS2 cathodes anionic redox high specific energy operating life |
| ISSN号 | 1944-8244 |
| DOI | 10.1021/acsami.0c13396 |
| 英文摘要 | Transition-metal sulfides are key cathode materials for thermal batteries used in military applications. However, it is still a big challenge to prepare sulfides with good electronic conductivity and thermal stability. Herein, we rapidly synthesized a Co-doped NiS2 micro/nanostructure using a hydrothermal method. We found that the specific capacity of the Ni1-xCoxS2 micro/nanostructure increases with the amount of Co doping. Under a current density of 100 mA cm(-2), the specific capacity of Ni0.5Co0.5S2 was about 1565.2 As g(-1) (434.8 mAh g(-1)) with a cutoff voltage of 1.5 V. Owing to the small polarization impedance (5 m Omega), the pulse voltage reaches about 1.74 V under a pulse current of 2.5 A cm(-2), 30 ms. Additionally, the discharge mechanism was proposed by analyzing the discharge product according to the anionic redox chemistry. Furthermore, a 3.9 kg full thermal battery is assembled based on the synthesized Ni0.5Co0.5S2 cathode materials. Notably, the full thermal battery discharges at a current density of 100 mA cm(-2), with an operating time of about 4000 s, enabling a high specific energy density of around 142.5 Wh kg(-1). In summary, this work presents an effective cathode material for thermal battery with high specific energy and long operating life. |
| WOS关键词 | ELECTROCHEMICAL PERFORMANCE ; ANIONIC REDOX ; FES2 CATHODE ; TECHNOLOGY ; DISCHARGE ; COS2 ; TEMPERATURE ; STABILITY ; ANODE ; COMPOSITE |
| 资助项目 | Military Electric Energy Program of Equipment Development Department of People's Republic of China Central Military Commission[4142110304] ; Natural Science Foundation of Guangdong Province[2018B030322001] ; Shenzhen Peacock Plan[KQTD2016022620054656] |
| WOS研究方向 | Science & Technology - Other Topics ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000592481300016 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | Military Electric Energy Program of Equipment Development Department of People's Republic of China Central Military Commission ; Natural Science Foundation of Guangdong Province ; Shenzhen Peacock Plan |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/43145]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Shi, Bin; Huo, Hua; Lu, Zhouguang |
| 作者单位 | 1.Tianjin Univ, Sch Mat Sci & Engn, Tianjin 300072, Peoples R China 2.State Key Lab Adv Chem Power Sources, Zunyi 563003, Guizhou, Peoples R China 3.Harbin Inst Technol, Sch Chem & Chem Engn, Harbin 150001, Peoples R China 4.Chongqing Univ, Sch Chem & Chem Engn, Chongqing 400044, Peoples R China 5.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 6.Southern Univ Sci & Technol, Dept Mat Sci & Engn, Guangdong Prov Key Lab Energy Mat Elect Power, Shenzhen 518055, Peoples R China |
| 推荐引用方式 GB/T 7714 | Guo, Hao,Tang, Licheng,Tian, Qianqiu,et al. Cobalt-Doped NiS2 Micro/Nanostructures with Complete Solid Solubility as High-Performance Cathode Materials for Actual High-Specific-Energy Thermal Batteries[J]. ACS APPLIED MATERIALS & INTERFACES,2020,12(45):50377-50387. |
| APA | Guo, Hao.,Tang, Licheng.,Tian, Qianqiu.,Chu, Ying.,Shi, Bin.,...&Lu, Zhouguang.(2020).Cobalt-Doped NiS2 Micro/Nanostructures with Complete Solid Solubility as High-Performance Cathode Materials for Actual High-Specific-Energy Thermal Batteries.ACS APPLIED MATERIALS & INTERFACES,12(45),50377-50387. |
| MLA | Guo, Hao,et al."Cobalt-Doped NiS2 Micro/Nanostructures with Complete Solid Solubility as High-Performance Cathode Materials for Actual High-Specific-Energy Thermal Batteries".ACS APPLIED MATERIALS & INTERFACES 12.45(2020):50377-50387. |
入库方式： OAI收割
来源：过程工程研究所
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