Inducing two-dimensional single crystal TiN arrays with exposed {111} facets by a novel chemical vapor deposition with excellent electrocatalytic activity for hydrogen evolution reaction
文献类型：期刊论文
| 作者 | Xiang, Maoqiao4,5; Song, Miao1,4; Zhu, Qingshan1,2,4; Yang, Yafeng4,5; Hu, Chaoquan4,5; Liu, Zhiwei3; Zhao, Hongdan1,4; Ge, Yu4 |
| 刊名 | CHEMICAL ENGINEERING JOURNAL
 |
| 出版日期 | 2021-01-15 |
| 卷号 | 404页码:8 |
| 关键词 | Induction-inhibition strategy Chemical vapor deposition Titanium nitride Nanosheets Hydrogen evolution reaction |
| ISSN号 | 1385-8947 |
| DOI | 10.1016/j.cej.2020.126451 |
| 英文摘要 | Two-dimensional (2D) single crystal transition metal nitrides (TMNs) with exposed active crystal planes have great value for fundamental science and technological applications. However, it is still a great challenge to synthesize the non-layer crystal structured 2D single crystal TMNs, e.g. the face-centered cubic (FCC) 2D single crystal TiN, which would have distinct properties. Herein, for the first time, an induction-inhibition strategy was successfully developed to break through the intrinsic limitation and the weak anisotropic growth tendency of the FCC TiN. Single-crystalline TiN nanosheet (about 5.14 nm thickness) arrays with exposed {111} active facets were synthesized successfully on a large scale by the new strategy, where the layer arrays were induced by a layered TiNCl intermediate formed by the chemical vapor deposition reaction of a new titanium source (TiCl3) with NH3 and the exposed {111} facets was caused by the chemisorbed Cl inhibitor. The special 2D single crystal TiN arrays exhibited excellent catalytic activity and durability for hydrogen evolution reaction (HER) from water electrolysis. |
| WOS关键词 | MOS2 ULTRATHIN NANOSHEETS ; PHASE GROWTH ; CHEMISORPTION ; MESOCRYSTALS ; CRYSTALLIZATION ; TEMPERATURE ; NITRIDES ; GRAPHENE ; TIC(111) ; CARBIDES |
| 资助项目 | Key Research Program of Frontier Sciences, Chinese Academy of Sciences[ZDBS-LY-JSC041] ; National Natural Science Foundation of China[11805227] ; Key Research Program of Nanjing IPE Institute of Green Manufacturing Industry[E0010708] ; Innovation Academy for Green Manufacture, Chinese Academy of Sciences[IAGM-2019-A11] |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000609010200003 |
| 出版者 | ELSEVIER SCIENCE SA |
| 资助机构 | Key Research Program of Frontier Sciences, Chinese Academy of Sciences ; National Natural Science Foundation of China ; Key Research Program of Nanjing IPE Institute of Green Manufacturing Industry ; Innovation Academy for Green Manufacture, Chinese Academy of Sciences |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/43323]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Zhu, Qingshan; Yang, Yafeng |
| 作者单位 | 1.Univ Chinese Acad Sci, 19 A Yuquan Rd, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Innovat Acad Green Mfg, 1 North Second St, Beijing 100190, Peoples R China 3.Beijing Univ Technol, Coll Mat Sci & Engn, 100,Pingleyuan, Beijing 100124, Peoples R China 4.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 5.Nanjing IPE Inst Green Mfg Ind, 266 Chuangyan Rd, Nanjing 211135, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xiang, Maoqiao,Song, Miao,Zhu, Qingshan,et al. Inducing two-dimensional single crystal TiN arrays with exposed {111} facets by a novel chemical vapor deposition with excellent electrocatalytic activity for hydrogen evolution reaction[J]. CHEMICAL ENGINEERING JOURNAL,2021,404:8. |
| APA | Xiang, Maoqiao.,Song, Miao.,Zhu, Qingshan.,Yang, Yafeng.,Hu, Chaoquan.,...&Ge, Yu.(2021).Inducing two-dimensional single crystal TiN arrays with exposed {111} facets by a novel chemical vapor deposition with excellent electrocatalytic activity for hydrogen evolution reaction.CHEMICAL ENGINEERING JOURNAL,404,8. |
| MLA | Xiang, Maoqiao,et al."Inducing two-dimensional single crystal TiN arrays with exposed {111} facets by a novel chemical vapor deposition with excellent electrocatalytic activity for hydrogen evolution reaction".CHEMICAL ENGINEERING JOURNAL 404(2021):8. |
入库方式： OAI收割
来源：过程工程研究所
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